基质固相分散辅助加速溶剂萃取-气相色谱法测定花生中有机磷农药残留.pdfVIP

※分析检测 良晶科学 2010,VoL31，No．22427 基质固相分散辅助加速溶剂萃取一气相色谱法 测定花生中有机磷农药残留 于辉，史俊稳，赵萍· (北京吉天仪器有限公司，北京 100015) 摘要：基质固相分散辅助加速溶剂萃取一气相色谱法测定花生中5种有机磷农药残留。花生样品与硅藻土、弗罗 里硅土混合后装填萃取池，加速溶剂萃取仪在10．0MPa、80℃条件下，丙酮作为提取溶剂，加热5min，静态提 0．038mg／kg。该法具有良好的分离效果、较宽的线性关系和较高的灵敏度。 关键词：加速溶剂萃取；气相色谱；有机磷农药；基质固相分散 Determinationof Pes乱ideResiduesinPeanutAssisted Accelerated Organophosphorus by Solid-phaseDispersion SolventExtraction·Gas Chromatography YUHui，SHIJun-wen，ZHAO Ping· TitanIns仉lmcnts 03eijing Co．Ltd．，Beijing100015，China) Abstract：Five residuesfrom we把determined pesticide peanut dispersion-assisted organophosphorus byusingsolid-phase with with anddiatomitetO acceleratedsolventexuaction we∞mixedflodsil coupledgaschromatography．Thepeanutsamples 衄theextractioninstnmmnLExtractionwas withacetoneat10．0MPaand80℃for 5rainandstaticextraaion performed heating 5rain．Elutionwas spiked rates aaalyzedwithGc-NPDdetector．Atthesamplelevelsof0．05Ing俺and0．1mg／kg，therecovery were88．2％一104．5％witha standard than residues relative deviationless 7．1％andthedetection oforganophosphomspestidde limit methodhasexcellent wide ofO．030—0．038 mg／：kg．This resolution,highsensitivity，good口∞isi舯aadlineadty． words：acceleratedsolvent