《ATC001电感耦合等离子体原子发射光谱分析技术》简介.pdfVIP

陈永欣 ，黎香荣，韦新红，等 ．碰撞反应界面 电感耦合等离子体质谱法测定磷酸 中 15种痕量杂质元素 冶金分析 ，2012，32(12)：15—21 Determinationoffifteentraceimpurityelementsin phosphoricacidbycollisionreaction interface-inductively coupledplasmamassspectrometry CHEN Yong—xin，LIXiang—tong，WEIXin—hong， HAN Qing-juan，CUIXiang，HELong—liang (FangchenggangEntry-ExitInspectionandQuarantineBureau，Fangchenggang538001，China) Abstract：ThereiSseriousinterferencefrom polyatiomicionsinthedeterminationofimpurityelements inphosphoricacidbytraditionalinductivelycoupledplasmamassspectrometry (ICP—MS)．Inthispa— per，the interferencewaseffectively eliminatedorreducedby collision reaction interfacetechnique (CRI)．Theexperimentsindicatedthat，afterthephosphoricacidsamplewasdiluteddirectly，thein— strumentsignalshiftandmatrixeffectcouldbecompensatedwith∞Y一 In一。。Biasinterna1standard elements；Mg，A1，Sr，CdandPbcouldbedeterminedbynonCRImode；thespectralinterferenceof V ，Cr，Mn，Co，Ni，Cu，ZnandAscouldbeeliminatedwithHeasreactiongas，andtheoptimalflow rateofHewasoptimizedas90mL／min；thespectralinterferenceofFeandSecouldbeeliminated withH2asreactiongas，andtheoptimalflowrateofH2wasoptimizedas70mL／min．Detectionlimits ofthismethodwere0．5-10ng／g，andtherecoveriesofstandardadditionwere80 一120 ．Thepro— posedmethodwasappliedtodetermineindustrial—levelandfood—levelphosphoricacidssamples．The resultswereconsistentwith thoseobtainedbyothermethods，and therelativestandard deviations (RSD)werelessthan6．6 (一6)，whichcouldmeettherequirementforbatch sampleanalysis． Keywords：phosphoricacid；impurityelements；inductively coupledplasmamassspectrometry；colli— Sion reactjon ((ATCO01电感耦合等离子体原子发射光谱分析技术》简介 ((ATCO01电感耦合等离子体原子发射光谱分析技术》系全国分析 检测人员能力培训委员会 (NTC)系列培训教材之一．本书内容主要包 括 ICP-AES分析技术的基础理论知识、仪器设备与操作、标准方法与