《光谱分析仪器使用与维护》.pdfVIP

第 1期 陈晓盼等：用于等离子体质谱的低成本可拆卸式直接注入高效雾化器 15l atthetip)，ahollowstainlesssteeltubing(0．5mm i．d．and2．0mmo．d．)andtwoadaptersmadefrom polytetrafluoroethylene ( FE)，which were assembled by epoxyresin．The tapered capillary was reproduciblyfabricatedaccording toaflame—heated two—step drawingmethod．Afterimmerging intoboiling water，theepoxyresin becamesoft andthecomponentscouldbetakenapart simply．Then thebrokenor blockedsamplecapillary wasreplacedbyanew taperedcapillary withthesamedimensionsandthentheywere assembledagain．Theoptimalsensitivitywasobtainedwhenthegasflowratewas0．27L／minwithasample uptakerateof50~tL／minandaforwardpowerof1500W ．Thesensitivities，detectionlimitsandprecisionsof thehomemadeDIHEN underoptimaloperatingconditionsaresimilar，orbetterthanthoseobtainedwiththe MicroMistnebulizer，tosomeextent，thoughthepolymericionlevelsoftheformerarehigherthanthoseofthe latter．TheutilityofthehomemadeDIHEN fortheanalysisofsmall—volumesampleswasdemonstratedby microscaleflowinjectionanalysisofPtinserumsamples．ThenthehomemadeDIHENwasfurtherutilizedto couplemicrochipelectrophoresistoICP-MSofriodinespeciation．ThecostofthehomebuiltDIHEN isabout 1％ priceofthecommercial MeinhardDIHEN．andthedemountableconstructionpemr itsthattheblockedor brokensamplecapillary couldbeconvenientlyrenewedwiththesamecapillary indimensions，obtaininglow costandeasymaintenance． Keywords Demountabledirectinjection high—efficiencynebulizer；Inductivelycoupledplasmamass spectrometry (Received5July2012；accepted10September2012) +_量 童 +_ +-量 量 圣+-圣 +- +_ 毒 《光谱分析仪器使用与维护》 (化学分析工程师实用技术丛书，ISBN978-7·1224)9323-3) 该书全面、系统地介绍了目前市面上流行的各类光谱分析仪器的使用与维护，每类仪器主要从仪器定性定量原理、 仪器结构与组成、仪器安装与调试、仪器操作与使用、仪器维护与保养、仪器维修与故障排除等方面进行阐述，重点在于 介绍仪器一线操作技术人员多年来的有关仪器操作和维护保养 、故障排除等方面的经验 ，同时，对于仪器操作过程中一 些注意事项也做了介绍。该书适合于我国专业检测机构和企业检测等