废乳化液处理.docVIP

管式共凝聚混凝气浮与生物氧化组合工艺 处理废乳化液的研究 费庆志1，李福忠2 （1．大连交通大学 环境与化学工程学院，116028；2.大连交通大学环境与化学工程学院，116028） 摘 要：随着机械制造业的快速发展，乳化液用量迅速增加.排放的废乳化液会对环境造成污染和损害，研究推广有效合理的废液处理技术，已成为一个重要课题.本实验研究中先利用实验确定了最佳PAC的投药量2g/L、PAM的投药量0.03/L，pH值8.5左右效果最好.然后利用管式共凝聚气浮法进行了乳化液破乳实验，由此确定适合的混凝气浮操作条件.经过管式共凝聚气浮处理原水COD由2.2104mg/L降到0.2104mg/L左右，SS由1716mg/L降到189mg/L左右.之后利用生物接触氧化技术对管式共凝聚气浮后的出水进行处理，最后的出水COD在330mg/L左右.根据实验结果，确定了“管式共凝聚气浮+生物接触氧化”工艺处理乳化液废水的可行性. 关键词：乳化液;管式共凝聚气浮;生物接触氧化 Abstract:With the rapid development of machinery manufacturing, emulsion in machining has been widely applied. Emissions of waste emulsion causes environmental pollution and damage.Research to promote effective and rational waste processing technology, has become an emulsion study of an important subject.In the experimental study, the first use of pilot-plant testing to determine optimal dosing coagulants PAC dosage of 2g / L, PAM of the optimum is 0.03/L, and the pH value on the mixed coagulation effect and to determine the pH value of about 8.5 when the coagulation best results. Then with the pilot test, according to the results of the use of tube-coagulation flotation method of the emulsion, to determine process conditions, etc., thus to determine a suitable flotation operating conditions. After tube-coagulation flotation treatment of raw water COD by 2.2 104mg / L down to 0.2104mg / L or so, SS from 1716mg / L down to 189mg / L or so. After the use of biological contact oxidation technology for tube-type of pool water after flotation processing, the final effluent COD in the 330mg / L or so. According to the experimental results, to determine the “tube-coagulation floatation + biological contact oxidation”process dealing with emulsion wastewater feasibility. Key words：emulsion tube-coagulation floatation Bio-contact oxidation 0引言 当前，世界机械制造工业是以切削、磨削与铸锻造三大加工工艺为主要支柱的。其中，切削加工的应用比例最高，约占机械加工总劳动量的30%～40%52%[1-3]，机械加工工业在车、磨、削、轧等加工过程中，普遍使用切削液来冷却、润滑、清洗、防锈，以提高产品的质量，延长机床的使用寿命。随着现代机械制造业的快速发展，切削液在机械加工中得到更为了广泛应用，用量迅速增加。但由于切削液会对环境和人体造成污染和损害，因此切削液