功能材料纯镍钴酸锂与掺杂后的电化学阻抗谱及红外光谱的探讨_钟耀东.pdfVIP

14 5 Vol1 14, No1 5 2 0 0 7 10 Metallic Functional Materials October, 2007 1, 2 2 1 钟耀东 , 赵新兵, 强颖怀 ( 11 , 221116; 21 , 310027) : , X ,, , , ( Ni, o) O ,, H , H , - O, O O 6 2 3 2 , , , : ; ;; :TM206 : A : 1005- 8192(2007)05- 0024- 04 A Study of Functional Materials about Pure and Doped Lithium Nickel Cobalt Oxides on Their lectrochemical Impedance Spectra and Fourier Transform Infrared Spectra1 1, 2 2 1 ZHONG Yao-dong , ZHAO Xin-bing , QIANG Ying-huai (11 School of Materials Science and Engineering, hina University of Mining and Technology, Xuzhou 221116, hina; 21 Department of M aterials Science and Engineering Zhejiang University, Hangzhou 310027, hina) ABSTRACT: Pure and doped lithium nickelcobalt oxides were synthesized by solid- state reaction1 X-ray diffraction patterns show that the crystallization is very well and there is no mixing betw een Li ion and ( Ni, o) ions1 Their Fourier transform infrared spectra w ere very similar1 The as- calcined spectra contained Li O and ( Ni, o) O 2 3 6 peaks1 How ever, the peaks of H , H , - O,O O could be found after charge/ discharge cycling1 Although the 2 3 2 solution resistance w as not changed after char