基于差示量热技术的生物质热解两步连续反应模型研究.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) 786 Acta Phys. Chim. Sin., 2006, 22(7) ：786 790 July [Article] 基于差示扫描量热技术的生物质热解两步连续反应模型研究 陈海翔 刘乃安* 范维澄 (中国科学技术大学火灾科学国家重点实验室, 合肥 230026) 摘要 采用差示扫描量热分析仪对我国的一种生 质试样在空气气氛中进行了实验, 发现试样从常温到923 K 高温的低速升温过程中, 经历了两步明显的放热过程. 对放热机理的分析表明, 第一步主要是由半纤维素和纤维 素的有氧热解过程控制, 第二步放热过程则受木质素热解和炭的氧化反应的共同作用. 采用等 化率方法和优 化计算方法, 对热解过程的动力学模型进行了研究, 结果表明, 两步连续反应机理可用于描述生物质在空气气氛 中热解的放热动力学. 关键词: 生物质, 热解, 动力学模型, 差示扫描量热 中图分类号： O643 Two step Consecutive Reaction Model of Biomass Thermal Decomposition by DSC CHEN, Hai鄄Xiang LIU, Nai鄄An* FAN, Wei鄄Cheng (State Key Laboratory of Fire Science, University of Science and Technology of China, Hef ei 230026, P. R. China) Abstract The thermal decomposition of one kind of biomass in air has been investigated by differential scanning calorimetry (DSC) analyzer. The results indicate that the heating process of samples from ambient temperature to 923 K at low heating rates show two obvious exothermic peaks. According to the decomposition mechanism, the first exothermic step is attributed to oxidative degradation of hemicellulose and cellulose, and the second exothermic step is attributed to lignin degradation and char oxidation. The reaction model of the studied biomass thermal decomposition has been studied by iso鄄conversional methods and optimization computation. The results suggest that the two鄄step consecutive reaction model is suitable to describe the exotherm of biomass thermal decomposition in air. Keywords