铂碳电极苯%2f水体系阴极反应规律研究.pdfVIP

铂碳电极苯/水体系阴极反应规律的研究 1 1,2* 黄海燕 ，俞英 1、中国石油大学（北京）化学科学与工程学院，北京 102249 2 、中国石油大学（北京）重质油国家重点实验室，北京 102249 摘要：水电解制氢- 电催化苯加氢耦合是实现制氢-储氢一体化的新技术。本文以铂碳气体扩散电极 为基础，研究了苯/水体系阴极电催化加氢反应的动力学基本规律，结果表明：随着苯蒸气浓度的增 加，加氢电流呈逐渐增加的趋势，当苯蒸气浓度增至 25%左右时，加氢电流的上升趋势减缓；随着 反应温度的升高，加氢电流持续增加，苯加氢反应的表观活化能为 32.88kJ/mol，析氢反应的表观活 化能为 18.08kJ/mol；随着阴极电势的增加，加氢电流在-1.0V 出现一个最大值，而后略有下降，而 析氢电流持续增加。 关键词：电催化；苯加氢；动力学；储氢 中图分类号: TK91 文献标识码: A Preparation of Ag/Nafion Electrode for Electrocatlytic Hydrogenation of Benzene 1 1,2 Huang Hai-Yan , Yu Ying * 1、Faculty of Chemical Science and Engineering, China Petroleum University, Beijing 102249 2 、The State Key Laboratory of Heavy Oil Processing, China Petroleum University, Beijing 102249 Abstract ：The electrochemical coupling of water electrolysis and benzene hydrogenation reaction on platinum carbon (Pt-C) electrode was studied in the paper. The rules of reaction rate of electrochemical benzene hydrogenation were summarized through inspecting the influence of different reactant concentration, the reaction temperature and the cathode potential to the electrocatalytic hydrogenation reaction rate. The result of experiment displays that with the reactant concentration increasing ，the electrocatalytic benzene hydrogenation reaction rate increases, however, the increasing tendency slows down while the reactant concentration reaches 25%; with the reaction temperature rising, the hydrogenations reaction rates speed up; activation energy of hydrogenations reaction is 32.88kJ/mol and activation energy of hydrogen evolution reaction is 18.08kJ/mol; with the step-down