TFTTP作为阴极缓冲层提高有机薄膜太阳能电池的内建电场和载流子收集效率.pdfVIP

CHINESE J0URNAL 0F CHEM ICALPHYSICS VOLUM E 27，NUM BER 5 OCTOBER 27，2014 ARTICLE SignificantEnhancementinBuilt—inPotentialandCha eCarrierCollection ofOrganicSolarCellsusing4一(5一hexylthi0phene一2一yI)一2，6一bis(5一 trifluoromethy1)thiophen--2--y1)pyridineasaCathodeBufferLayer YueZang，Kang—liCao，JiangHuang。，QingZhang ，Jun—shengYu。 a． 5tateKeyLaboratory ofElectronicThin |m and IntegratedDevices．SchoolofOptoelectronic Information，UniversityofElectronicScienceandTechnologyofChina，Chengdu510054，China b．DepartmentofPolymerScience，SchoolofChemistryandChemicalTechnology,ShanghaiJiao ，Ig University,Shanghai200240,China (Dated：ReceivedonMay8，2014；AcceptedonJuly21．2014) An electron transporting material of TFTTP (4一(5-hexy1thiophene一2一y1)一2，6一bis(5一 trifluoromethv1)thiophen一2一y1)pyridine1wasinvestigatedasacathodebufferlayertoenhance thepowerefficiencyoforganicsolarcells(OSCs)basedonsubphthalocyanineandC6o．The overallpowerconversione伍ciencywasincreasedbyafactorof1．31byinsertingtheTFTTP interfaciallaverbetween theactivelayerand metalliccathode．The innermechanism re— sponsiblefortheperformanceenhancementofOSCswassystematically studiedwiththe simulationofdarkdiodebehaviorandopticalfield distributioninsidethedevicesaswell asthecharacterization ofdevicephotocurrent．Theresultsshowed thattheTFTTP 1ayer could significantly increasethebuilt—in potentialin thedevices，leadingto theenhanced dissociationofchargetransferexcitons．Inaddition，byusingTFTTP as thebufferlayer， abetterOhmiccontactatC6n／metalinteffacewasformed，facilitatingmoreemcientfree chargecarriercollection． Keywords：Organicsolarcells，Cathodebufferlayer，Built—in potential，Chargecarrier collection，Opticalspacereffect I．1NTR0DUCT10N ties．Firstly．suchtr