田黄的红外和拉曼光谱研究.pdfVIP

田黄的红外与拉曼光谱研究 刘云贵1陈涛1,2 1.中国地质大学珠宝学院，武汉，430074 2.中国地质大学地质过程与矿产资源国家重点实验室，武汉，430074 本文对中国寿山田黄石进行了X射线粉晶衍射(XRD)、红外光谱和拉曼光谱测试，以获得田黄的谱学特征。研究表明 田黄有地开石质、珍珠陶石质和伊利石质三类，其红外特征吸收峰分别为3621cm-1、3629cm-1和3631cm-1，拉曼特征峰分别 为3626cm-1、3627cm-1和3632cm-1，3550cm-1～3750cm-1间OH振动所致拉曼谱峰与红外结果一致。地开石质田黄含无序、 有序两类，无序地开石OH3振动吸收峰相对有序地开石向低波数方向移动8cm-1，相对强度增强，无序结构可能与高含量 的Fe有关。3550cm-1～3750cm-1间地开石OH振动红外吸收峰强于珍珠陶石，表现为珍珠陶石质田黄的红外光谱明显叠加 有副矿物地开石的强吸收峰。伊利石质田黄主要为2M1型伊利石，并含有少量1M型伊利石。这些特征为科学鉴定田黄提 供了理论依据。 田黄；XRD；红外光谱；拉曼光谱 InfraredandRamanSpectraStudyonTianhuang YunguiLiu1TaoChen1,2 1.GemmologicalInstitute,ChinaUniversityofGeosciences,Wuhan430074.China;2.StateKeyLaboratoryofGeologicalProcess esandMineralResources,ChinaUniversityofGeosciences,Wuhan430074.China. TheTianhuangstones,fromShoushaninChina,havebeenstudiedbyusingX-rayPowderDiffractometry(XRD),Infrared (IR)spectroscopyandRamanspectroscopytoobtainthespectracharacterization.3621cm-1,3629cm-1,3631cm-1intheIRspectra and3626cm-1、 3627cm-1,3632cm-1intheRamanspectraarethecharacteristicpeaksofdickiticTianhuang,nacriticTianhuangand illiticTianhuang,respectively.RamanspectraassignedtoOHaregoodagreementwiththeIRresultsat3550cm-1～3750cm-1.Dickitic Tianhuangincludesordereddickiticanddisordereddickitic.Comparedwithordereddickite,thebandassignedtoOH3ofdisordered dickiteshiftstolow-frequencyby8cm-1andtherelativeintensitybecomesstronger.Thedisorderstructuremayrelatetothehigh levelofFe.TheIRabsorptionspectraofnacriticTianhuangsuperimposesstrongpeaksofdickite,indicatingthatIRabsorptionbands ofdickitearestrongerthanthatofnacriteat3550cm-1～3750cm-1.ThemainmineralcompositionofilliticTianhuangis2M1,while illiteTianhuangcontainsasmallamountof1M.Allthesecharactersprovideatheoreticalbasisforthescientificidentificationof Tianhuang. Keywords:Tianhuang;XRD;IRspectroscopy;Ramansp