铁炭微电解%2fFenton氧化改善嘧啶废水可生化性研究的论文.pdfVIP

2008 年给水厂、污水厂运行与管理及升级改造高级研讨会论文集 铁炭微电解/Fenton 氧化改善嘧啶废水可生化性研究 安莹，孙力平，陈修辉 （天津城市建设学院环境与市政工程系，天津 300384 ） 摘 要：采用曝气铁炭微电解-Fenton 氧化法处理维生素 B1 厂嘧啶生产段废水，得出最佳工 况条件：铁炭体积比为 0.5、进水 pH值为 5、曝气时间为 2h、充水体积比为 0.5、气水体积比为 200；H O 投加量为 5mL/L、氧化 pH 值为 3、氧化时间为 90min。试验结果表明，该组合工艺对废 2 2 水 COD去除率达到 55%以上，m(BOD )/m(COD )由 0.140提高到 0.325，提高了废水的可生化性。 5 Cr 关键词：嘧啶废水；铁炭微电解；Fenton氧化；维生素 B Pretreatment of Pyrimidine Production Wastewater by Iron-carbon Microelectrolysis-Fenton Oxidation Process AN Ying ，SUN Li-ping，CHEN Xiu-hui (Department of Environmental and Municipal Engineering，Tianjin Institute of Urban Construction ， Tianjin 300384，China) Abstract ：Aeration and iron-carbon microelectrolysis-Fenton oxidation process was used in treatment of pyrimidine wastewater from vitamineB1 factory, and the optimum conditions were obtained: . the vol. ratio of iron to carbon was 0.5、feeding pH was 5、aeration time was 2 hours、the vol. ratio of wastewater to padding was 0.5 、the vol. ratio of gas to wastewater was 200; the addition of H O 2 2 was 5mL/L 、oxidation pH was 3、oxidation time was 90 minutes. The results showed that the removal rate of COD was over 55% ，m(BOD )/m(COD )was enhanced from 0.140 to 0.325, and the capability 5 Cr of biochemistry was also improved. Key words ：pyrimidine wastewater ；iron-carbon microelectrolysis ；Fenton oxidation ；vitamineB1 在生产维生素 B1 的过程中排放出相当数量含有害物质的生产废水，而嘧啶废水是各阶段所产 废水中最难处理的高浓度有机废水，其中主要含乙酰嘧啶，盐酸乙醚及 20% NaCl，对水环境造成 了严重的威胁。目前，国外对该类废水处理的报道较为罕见，国内大部分生产企业一般将生产废 - 258 - 2008 年给水厂