磷酸改性凹凸棒粘土对Pb-%272%2b-地吸附研究.pdfVIP

磷酸改性凹凸棒粘土对Pb2+ 的吸附研究∗ 周守勇 薛爱莲 张艳 王红艳 赵宜江** (淮阴师范学院化学系, 江苏省低维材料化学重点建设实验室，江苏淮安, 223001) 摘 要：采用不同浓度磷酸对凹凸棒石粘土进行改性，测定了改性粘土的氮气吸附-脱附等温 线、BET 比表面积、孔径分布、孔容和平均孔径，在此基础上，研究了改性凹凸棒石粘土 对水中Pb2+ 的吸附。结果表明，磷酸改性凹凸棒石粘土具有典型的中孔特征，改性后比表面 积和孔容明显增大，可以获得平均孔径在3.9nm 左右的中孔材料。改性凹凸棒粘土对铅离子 的吸附效果明显好于原土，其中9mol/L 磷酸改性处理的凹凸棒粘土吸附能力最佳，在水样 pH=5 ，粘土加入量为20～30g/L 废水中，接触时间20 分钟，铅离子浓度10 mg/L 时，Pb2+ 的被吸附率接近99% 。改性凹凸棒石粘土对铅离子的吸附，符合Langmuir 吸附等温方程， 饱和吸附量约为 10.0 mg/g。 关键词：凹凸棒土 改性 含铅废水 吸附 2+ Adsorption of Pb on Attapulgite Modified by Phosphoric Acid Zhou Shouyong Xue Ailian Zhang Yan Wang Hongyan Zhao Yijiang (Department of Chemistry，Huaiyin Teachers College ， Jiangsu Huaian ， 223001) Abstract ：The nitrogen adsorption isotherms, BET surface area,pore size distribution, pore volume and average pore size of the H PO modified attapulgite were investigated by SA 3100 3 4 surface area and pore size analyzer. The results showed that the H3PO4 modified attapulgite showed obvious meso-porous distribution, larger surface area and pore volume,which was 2+ meso-porous materials with 3.9nm average pore size. Furthermore, adsorption of Pb on activated attapulgite was systematically studied. The results showed that the H PO modified attapulgite had 3 4 obviously better absorbtion effects than original attapulgite.The optimal absorption condition was the attapulgite been treated in 9mol/L H PO . The absoption rate reached 99% in the case of 3 4 2+ pH5,feeding amount of 20~30g/L, contacting time