锂离子电池用硅_碳复合负极材料_王保峰.pdfVIP

2003 61 Vol. 61, 2003 10 , 1572~ 1576 ACTA CHIMICA SINICA No. 10, 1572~ 1576 / 王保峰 杨 军 解晶莹 王 可 文钟晟 喻献国 ( 200050) ( PVC) , , PVC , . : - 1 84% , 700 mAh , 30 90% . , ( CMS) 015 V , . / , , , , Si/ C Composite Negative Electrode Material for Lithium Ion Batteries WANG, BaoFen YANG, Jun XIE, Jin Yin WANG, Ke WEN, Zhon Shen YU, XianGuo ( Shang hai Institute of Microsystem and Inf ormation Technology , Chinese A cademy of Sciences, Shanghai 200050 ) Abstract A novel Si/ C composite ne ative electrode for lithium ion batteries was obtained by pyrolyzin the mixture of polyvinyl chloride, nanoSi powder and fine artificial raphite particles. NanoSi and fine raphite are dispersed in carbon uniformly. Electrochemical test shows the first cycle efficiency of the composite is about 84% and the - 1 reversible capacity is about 700 mAh . The capacity retention at the 30th cycle is more than 90%. In addition, the char edischar e volta e plateau of the composite shifts toward positive direction for about 015 V a ainst that of the commercialized CMS ne ative electrode material, which is favorable for enhancin the char in rate and operatin safety of the cell. Key ords Si/ C composite, anode materials, lithium ion battery, lar e capacity, pyrolysis [ 4, 5] . , . ; , ( 372 mAh- 1 [ 1] ) , SnSb , SnCu , ; x x , ,