有机硅氧烷改性丙烯酸酯微乳液的合成的探究.pdfVIP

有机硅氧烷改性丙烯酸酯微乳液的合成研究 孙志娟 张心亚 黄洪 陈焕钦 (华南理工大学化工研究所，广东 广州 510640) 摘要:引入乙烯基三异丙氧基硅烷（C-1706）对丙烯酸酯乳液进行改性,采用种子乳液聚合法 制备高性能的硅丙微乳液。着重探讨了有机硅氧烷单体的种类及其滴加方式对乳液性能的影 响，发现以C-1706 为功能性单体可降低其在聚合过程中的水解反应活性，在保持聚合过程 稳定的同时又提高了乳液的贮存稳定性；采用硅氧烷的后滴加方式，可有效抑制乳液聚合过 程中硅氧烷的水解和缩合反应，将涂膜的吸水率降至2.6。此外，借助傅立叶红外光谱仪、 扫描电镜和透射电镜分析聚合产物的结构、涂膜的断面形态和共聚乳液的粒径及其分布，结 果表明改性后的硅丙微乳液的粒径可控制在50nm—70nm 之间，硬度为7.3，且引入1.5%的 C－1706 就可有效提高乳液的户外耐候性。 关键词：有机硅氧烷 硅丙微乳液 改性 性能 中图分类号：TQ433 文献表示码：A Synthesis of acrylate microemulsion modified with organosiloxane SUN Zhi-juan ZHANG Xin-ya CHEN Huan-qin (Research Institute of Chemical Engineering, South China University of Technology, Guangzhou,510641, china) Abstract: The acrylate emulsion was modified by adding vinyltriisopropoxy silane (C-1706), the acrylosilane microemulsion with high properties was synthesized by seeded emulsion polymerization. The monomer variety of alkoxy silane and its to be added method which influence on the properties of the microemulsion was investigated. It has been found that C-1706 can reduce hydrolysis reactivity during the polymerization process, so that it is not only to make the process smoothly but also advance the store stability of the emulsion; the latter-addition mode of C-1706 can restrain its hydrolysis activity and polycondensation reaction, the water absorption of the emulsion film is reduced to 2.6. Moreover, the structure, morphology and particles size distribution of the emulsion were analyzed by FT-IR, Scanning Electron Microscopy(SEM) and Transmission Electron Microscopic (TEM) respectively. The results show that the particle diameter of the modified microemulsion can be controlled between 50 and 70 nanometer and its film hardness is 7.3, and only adding 1.5% of C-1706 into the system of emulsion polymerization can apparently impro