微波辅助制备铝锆柱撑膨润土除氟性能的研究.pdfVIP

微波辅助制备铝锆柱撑膨润土除氟性能的研究 1 3 1 2 龙敏 ，唐艳葵 ，童张法 ，梁达文 (1.广西大学化学化工学院，广西 南宁 530004；2. 广西大学环境学院， 广西 南宁 530004； 3. 玉林师范学院化学与生物系，广西 玉林 537000 ) 摘要：用微波辅助制备锆铝柱撑膨润土(MZAPB)，考察其对水溶液中F- 的吸附行为，并借助扫描电子显微 镜（SEM ）对吸附前后铝锆柱撑膨润土进行表征，以探索其吸附机理。研究结果表明：室温条件下，在溶 液pH=5.6 中处理F-初始浓度为8 mg·L−1 的含氟水溶液，当吸附剂用量为8 g·L−1，吸附时间为40 min 后即 能达到吸附平衡，氟离子去除率可达97.85 % 。溶液初始pH 及溶液中共存离子的浓度是影响吸附效果的主 要因素。且高浓度的Fe3+及CO32-离子能明显抑制铝锆膨润土对氟的吸附。 关键词：微波；铝锆柱撑膨润土；氟；吸附 中图分类号：X506 文献标识码：A Removal of Fluoride from Aqueous Solution by Pillared Bentonite Synthesized under Microwave Irradiation 1 2 1 3 Long Min , Tang Yankui , Tong Zhangfa , Liang Dawen (1 School of Chemistry and Chemical Engineering, Guangxi University, Nanning, Guangxi 530004,China； 2 School of Environmental, Guangxi University, Nanning, Guangxi 530004,China ；3 Department of Chemistry and Biology, Yulin normal university, Yulin, Guangxi 537000 ,China ) Abstract ：Microwave aided synthesized Al-Zr pillared bentonite (MZAPB) which was synthesized under microwave irradiation was applied to remove fluoride in aqueous medium. MZAPB has been characterized by the SEM image analyses. Influence of pH, adsorbent dose and presence of other anions on fluoride adsorption by the MZAPB on the adsorption were −1 investigated. The removal rate of fluoride is 97.85% when initial concentration is 8 mg·L , pH is −1 5.6 and adsorbent dosage is 8 g·L , adsorption of fluoride reach equilibrium in 40 min. The influence of the initial pH was related to the prevailing mechanisms of defluoridation. The presence of