CoCrMo合金等离子体浸没离子注入与氮化工艺与其性能.pdfVIP

CoCrMo合金等离子体浸没离子注入及氮化工艺及其性能 周雪婧 李嫱 孙 鸿 冷永祥 黄楠 西南交通大学材料先进技术教育部重点实验室，材料科学与工程学院，四川成都610031 摘要：CoCrMo合金具有良好的机械性能和生物相容性，被广泛的应用在临床医学。为了进一步提高CoCrMo合 金的力学性能，本文采用高频低压脉冲等离子体浸没离子注入与氮化技术对CoCrMo合金进行氮离子注入及氮 化处理，着重研究了氮化气压对CoCrMo合金氮化改性后的结构和性能的影响。通过X射线衍射谱(XRD)研 究了CoCrMo合金氮化后的相结构，采用显微硬度仪、销-盘磨损实验分别研究了CoCrMo合金改性后的显微硬 度、摩擦磨损性能。研究结果表明，经氮化改性后，CoCrMo合金表面主要形成物为CO2N和Cr2N，氮化处理 能显著提高CoCrMo合金表面的显微硬度和耐磨性；并且氮化气压越低，改性层的硬度越高，耐磨性越好，较 低气压下(0.5Pa)进行氮化处理后CoCrMo合金的显微硬度提高一倍，耐磨性也有大幅度的提高。 关键词：CoCrMo合金；等离子体浸没离子注入与氮化;气压;耐磨性；硬度 ThemicrostructureandmechanicalpropertiesofCoCrMoalloys modifiedbyplasmaimmersionionimplantationandnitriding ZHOUXuejingLIQiangSUNHongLENGYongxiangHUANG Nan KeyLaboratoryforAdvancedTechnologiesofMaterials,MinistryofEducation,SchoolofMaterialsScienceand Engineering,SouthwestJiaotongUniversity,Chengdu610031,Sichuan,China Abstract:CoCrMoalloyswereextensivelyusedinclinicalmedicineforthesuperiormechanicalpropertyandbiocom patibility.InordertoincreasethewearresistanceoftheCoCrMoalloys,CoCrMoalloysweremodifiedbyhighfre quencylowvoltageplasmaimmersionionimplantationandnitridingatdifferentnitrogenpartialpressure.Theeffect ofnitrogenpartialpressureonthestructureandthepropertyoftheCoCrMoalloyswereinvestigatedinthisstud y.Themicrostructure,microhardnessandwearresistanceofthemodifiedCoCrMoalloyswerecharacterizedwithX raysdiffraction(XRD),HXD1000microhardnessmeterandCSEMpinondiskweartestapparatus.Theresults showedthatthesurfaceofthemodifiedCoCrMoalloyswasmainlycomposedofCo2NandCr2Nphase.Themicro hardnessandwearresistanceoftheCoCrMoalloyscanbegreatlyimprovedbynitridingtreatment.Thelowernitri dingpressurecouldinductbettermechanicalproperties.Whenthenitridingwascarriedat0.5Pa,themicrohardness ofthenitridingtreatmentCoCrMoalloyscouldbealmosttwotimesthanthatvirginCoCrMoalloysandthewearre sistancealsohadbeensignificantlyimproved. Keywords:CoCrMoalloys;plasmaimmersionionimplantationandnitriding;press