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Preparation of Hydrogen through Catalytic Steam Reforming of Bio-oil.pdf
维普资讯
第 7卷第6期 过 程 工 程 学 报 、,01.7No.6
2007年 l2月 TheChineseJournalofProcessEngineering Dcc.2007
PreparationofHydrogenthroughCatalyticSteam ReformingofBio—oil
wuCeng(吴 层),YANYong-jie(颜涌捷),LITing—then(李庭琛),QIWei(fr伟)
(DepartmentofEnergyChemicalEngineering,EastChinaUniversityofScienceandTechnology,Shanghai20023LChina)
Abstract:Hydrogenwaspreparedviacatalyticsteam reformingofbio—oi1whichwasobtainedrfom fastpyrolysisofbiomass
inafluidizedbedreactor.Influentialfactorsincludingtemperature,weighthourlyspacevelocity(WHSv)ofbio—oil,mass
ratioofsteam tobio—oil(S/B)aswellascatalysttypeonhyrdogenselectiviyt andotherdesirablegasproductswere
investigated.Basedonhydrogeninstoichiometricpotentialandcarbonbalna ceingaseousphaseandfeed,hydrogenyieldand
carbonselectiviytwereexamined.Theexperimentalresultsshowthathighertemperaturefavorsthehyrdogenselectiviytby
H2molerfactioningaseousproductsstream anditplaysanimportnatroleinhyrdogenyieldandcrabonselectiviyt.Higher
hyrdogenselectiviyt andyield,nadcarbonselectiviytwereobatinedatlowerbio—oilWHSV.Incaatlyticsteam reforming
system amaximum steam concenrtationvalueexists,atwhichhydrogenselectiviytnadyield,andcrabonselectiviyt keep
consatnt.Throughexperiments,preferentialoperationconditionswereobtainedasfollows:temperature800-850*C,bio·Oi1
WHSV below 3.0h~,andmassratioofsteam tobio—oil10-12.Theperfomr ancetestsindicatethatNi.basedcaatlystsare
optional,especiallyNi/ct—A1203effectiveinthesteam refomr ingprocess.
Keywords:fastpyrolysis;bio-·oil;hyrdogen;stema refomr ing;Ni-·basedcaatlyst;carbonselectiviyt
CLCNo.:TK6 DocumentCode:A
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