Degradation of Ester Lubricants.ppt

Degradation of Ester Lubricants Degradation of Ester Lubricants Part 2: The Oxidation of Polyol Esters Trimethylolpropane (TMP) Esters Trimethylolpropane (TMP) Esters Trimethylolpropane (TMP) Esters Trimethylolpropane (TMP) Esters Trimethylolpropane (TMP) Esters Oxidation of Ester Lubricants Trimethylolpropane (TMP) Esters Oxidation of Neopentylglycol Dibutanoate : GC Trace Oxidation of NPG Dibutanoate : Main Products Oxidation of NPG Dibutanoate : Diol Formation Oxidation of NPG Dibutanoate : Hydroxyesters Oxidation of NPG Dibutanoate : Esters of Hydroxyesters Oxidation of NPG Dibutanoate : α,β-Unsaturated Ester Formation of α,β-Unsaturated Ester Formation of α,β-Unsaturated Ester Formation of α,β-Unsaturated Ester Oxidation of NPG Dibutanoate : Cyclic Acetal Formation of Cyclic Acetals Formation of Cyclic Acetals Formation of Cyclic Acetals Trimethylolpropane (TMP) Esters Oxidation of TMP Tributanoate : GC Trace Oxidation of TMP Tributanoate : Main Products Oxidation of TMP Tributanoate : Transesterification Oxidation of TMP Tributanoate : Oxidation Products Oxidation of TMP Tributanoate : Cyclic Acetal Main Products of TMP Tributanoate Oxidation Main Products of TMP Tributanoate Oxidation Transesterification Products Transesterification Products : II Possible Hydrolysis of TMP Tributanoate? Water Content During Autoxidation Water Content During Autoxidation TMP Tributanoate Oxidation : Viscosity Increase Viscosity Increase : Correlation with TMP Dibutanoate Viscosity Increase : Correlation with TMP Dibutanoate Formation of High Molecular Weight Species Formation of High Molecular Weight Species : II Formation of High Molecular Weight Species : III Formation of High Molecular Weight Species : IV Trimethylolpropane (TMP) Esters TMP Trihexanoate vs. TMP Tributanoate Oxidation TMP Trihexanoate vs. TMP Tributanoate Oxidation Conclusions : Main Oxidation Mechanisms of Polyol Esters Conclusions : Main Oxidation Mechanisms of Polyol Esters Conclusions : Main Oxidat