木屑微波热解技术研究.pdfVIP

木屑微波热解技术研究 1 2 1 1 商辉 ，Sam Kingman , 周红军 ，徐春明 1：中国石油大学（北京）化学科学与工程学院重质油国家重点实验室 102200 ，2：School of Chemical and Environmental Engineering, University of Nottingham, Nottingham, NG7 2RD, UK 英国DEFRA 项目 摘要： 本课题利用微波热裂解的方法将木屑转化为生物能源，是一种非常有前景的处理和利用废 弃生物质转化为能源的工艺，考察了多模谐振腔和单模谐振腔对热裂解的影响，并研究了水含 量在微波加热下对木屑热裂解的影响，讨论了微波加热与传统加热下生物质热解机理。研究发 现单模谐振腔比多模谐振腔更有助于生物质的快速热解。孔隙中的水分是微波热解生物质的主 要因素，可以提高加热速率。生物质热解在微波加热与传统加热下的最大差别在于前者是由里 及外的加热，有利于可以减少二次反应的发生，提高生物油的收率和质量，固体产物—炭的性 质也得到了改善。热解油主要是由脂肪族含氧化合物和芳香烃类物质的复杂混合物，热解的气 体产物主要为CO、CO2、甲烷与乙烷。 关键词：微波，热裂解，生物质，木屑，生物能源 中图分类号：TK6 Technique Study on the Microwave Pyrolysis of Sawdust 1 2 1 1 Hui Shang , Sam Kingman , Hongjun Zhou , Chunming Xu (1: State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Beijing, 102249, China; 2: School of Chemical Environmental Engineering, University of Nottingham, Nottingham, NG7 2RD, UK) Abstract: The pyrolysis of sawdust using microwaves was studied as a potential technology for the application of biomass waste to produce high-value bio-energy. Microwave cavities as multimode and single mode were investigated, moisture content was examined for the influence of microwave processing. It was found that the pore water is the key factor to induce pyrolysis under microwave irradiation; the moisture content can highly increase the pyrolysis possibility and heating rate of the sample bulk. The pyrolysis products depend upon the treatment conditions and moisture content. The mechanism of microwave pyrolysis is quite different from conventional heating pyrolysis. In conventional method, wood is heated by convective heat transfer from hot gas and co