FeO_OH_C催化水合肼还原芳香族硝基化合物制备芳胺.pdfVIP

! 18 ! 2009 FeO( OH) / C , , ( , 221006) : 采用浸渍法制备了FeO( OH) / C 催化剂用X射线粉末衍射法对FeO( OH) / C 进行了表 征, 结果表明FeO( OH) 在活性炭中高度 散催化剂中FeO( OH ) 含量的增加能提高其催化活 性, 但过多的FeO( OH) 无法全部负载, 催化剂中FeO( OH) 的质量 数以10% 为宜催化剂具有 较好重复使用性, 重复使用8 次活性未明显下降在5 mL 乙醇中以0. 02 g 10%FeO( OH) / C 为 催化剂, 1. 0 mmol 芳香族硝基化合物和2. 0 mmol 水合肼于75 反应一定的时间, 芳胺的收率为 96. 3%~ 99. 5% : 氢氧化氧铁; 还原; 芳香族硝基化合物; 水合肼; 芳胺 : T Q 2 6. 3 : A : 2009) 070 1803 FeO( OH) / Ccat alyzed Reduction of Aromatic Nitro Compounds to Anilines w ith H ydrazine H ydrate CAI Keying, ZH OU Yingmei, YUE Wei ( S chool of Chemistr y and Che mical Eng ine ering , X uz hou I nst itu te of Te chnolog y , J iangsu X uzh ou 221006 , China Abstract: T he XRD patterns of FeO ( OH ) / C catalysts prepared by impregnation show ed that the active component FeO( OH) w as highly dispersed in active carbon. T he activity of the catalyst increased w ith the increase of FeO( OH) content in active carbon, but excessive FeO( OH) could not be loaded. The suitable content of FeO( OH) w as 10% in active carbon. T he catalyst had good reusability , and no deactivation w as observed after 8 times of recycle. Under the conditions of 1. 0 mmol of aromatic nitro compound, 2. 0 mmol of hydrazine hydrate, 0. 02 g of 10% FeO( OH) / C, 5 mL of ethanol, reacting at 75 for a period of time, anilines w ere prepared w ith 96. 3%~ 99. 5% yields. Key words: iron oxide hydroxide; reduction; aromatic nitro compounds; hydrazine hydrate; anilines [ 1, 2] , , Pd/ C , Raney N i ( ) , [ 35]