功能高分子纳米材料的制备及其催化性能33854.pdfVIP

理化学学报(Wuli Huaxue Xuebao) 900 Acta Phys. Chim. Sin., 2007, 23(6) ：900-904 June [Article] 功能高分子纳米材料的制备及其催化性能 佘世雄1,2 苏碧桃1, 杨 燕1 敏世雄1 雷自强1 1 ( 西北师范大学化学化工学院, 省部共建生态环境相关高分子材料教育部重点实验室, 甘肃省高分子材料重点实验室, 兰州 730070; 2 沈阳农业大学理学院, 沈阳 110161) 摘要： 将两种具有不同结构的共轭高分子聚糠醇 苯酚(PFP 0)及聚对苯撑(PPP 0)分别在一定条件下热活化处 理后, 成功地用作为染料废水处理 化剂PFP 及PPP; 利用DTA TG 、TEM 、FT IR 、UV Vis 等技术对样品进行了 表征. 结果表明, PFP 及PPP 在自然光照射及空气氧存在的温和条件下, 很短时间内就能使染料亚甲基蓝(MB)几乎 完全脱色降解和大部分矿化; 材料共轭结构对其稳定性能有较大的影响; 横向比较分析发现, 极性基团的存在, 对材料的 化性能有重要影响. 关键词：功能高分子; 纳米材料; 制备; 化性能 中图分类号： O643 Preparation of Functional Polymer Nanomaterial and Its Catalytic Property SHE Shi Xiong1,2 SU Bi Tao1, YANG Yan1 MIN Shi Xiong1 LEI Zi Qiang1 1 ( Key Laboratory of Eco Environment Related Polymer Materials of the Ministry of Education, Key Laboratory of Gansu Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, P. R. China; 2College of Science, Shenyang Agriculture Uuniversity, Shenyang 110161, P. R. China) Abstract ： After properly heat activating the polymers poly (furancarbinol co phenol) (PFP 0) and polyparaphenylene (PPP 0), two new functional polymer nanomaterials, PFP and PPP were obtained. Their properties as catalysts in water pollution treatment were studied. The samples were determined by means of DTA TG, TEM, FT IR, and UV Vis. The results showed that under natu