改性活性炭负载高分子季铵盐杀菌性能.pdfVIP

第 63卷 第 1期 化 工 学 报 Vo1．63 NO．1 2012年 1月 CIESC Journa1 January 2012 改性活性炭负载高分子季铵盐的杀菌性能 周静茹 ，裴丽霞，张立志 (华南理工大学化学与化工学院，传热强化与过程节能教育部重点实验室，广东 广州 510640) 关键词：活性炭；高分子季铵盐；杀菌；吸附 DOI：10．3969／]．issn．0438—1157．2012．01．040 中图分类号：TQ424．1 文献标志码 ：A 文章编号 ：0438—1157(2012)01—0286—06 Antibacterialpropertyofpolymericquaternaryammonium salt immobilizedonmodifiedactivatedcarbon ZHOUJingru，PEILixia，ZHANGLizhi (KeyLaboratoryofEnhancedHeatTrans{erandEnergyConservationofMinistryofEducation，SchooloJChemistry andChemicalEngineering，SouthChinaUniversityofTechnology，Guangzhou510640，Guangdong，China) Abstract：Polymericquaternaryammonium saltwasimmobilizedonactivatedcarbon (AC)，byoxidation ofAC with concentratednitricacid， subsequenteletrostaticassembly to producea high—performance bactericide (P—AC)withgoodadsorption． ThesurfacecharacteristicsofAC beforeandaftermodification wereanalyzedbyBoehm method．ThecompositionandmicrostructureofP—ACwerecharacterizedbyFTIR andTG．Theadsorption capacityoftheobtainedP—ACwastestedusingphenolasamodelcompound。and theantibacterialactivity againstE．coliwasalso measured．Theresults show that： (1) AC iswelI modifiedbyconcentrated nitricacid，carboxyland lactonegroupsofAC increasewhilethehydroxyl groupsdecrease： (2)Polymericquaternaryammonium saltwasimmobilizedonmodifiedACwith loading of12 (mass)，P—AC has1owerBET surfacearea and theporevolume thanAC，buthasthe larger averageporediameter； (3)P-AC exhibitsgoodadsorptionpropertyforphenol，whichis82．5 ofadsorption capacityofAC； (4)P—AC showsexcellentantibacterialproperty，anantibacterialefficiencyforE．coliof 99 canbeachievedoveraperiodof2hours．Andaslightdecreaseof5％inantibacterialefficiencycanbe observeda