锂离子电池PMMA_VAc聚合物电解质的制备与性质研究_卢雷.pdfVIP

2007 65 Vol. 65, 2007 6 , 475480 ACTA CHIMICA SINICA No. 6, 475480 · · PMMA-VAc a a *,a b a (a 510006) (b 510600) (MMA)(VAc), (PMMA-VAc), . (FTIR) (GPC)(DSC/TG)(SEM) . , MMA VAc C C PMMA-VAc. PMMA-VAc , PMMA-VAc , 4% . PMMA-VAc , . PMMA-VAc : 380 . PMMA-VAc 1.85103 S•cm1, , . ; PMMA-VAc; ; Study on the Preparation and Performances of PMMA-Vac Polymer Electrolyte for Lithium Ion Battery Use LU, Leia ZUO, Xiao-Xia LI, Wei-Shan*,a LIU, Jian-Shengb XU, Meng-Qinga a ( School of Chemistry and Environment, South China Normal University, Guangzhou 510006) (b Guangzhou Tinci High-Tech Materials Co., Ltd., Guangzhou 510600) Abstract A copolymer, poly-methyl methacrylate-vinyl acetate (PMMA-VAc), was synthesized by emul- sion polymerization with methyl methacrylate (MMA) and vinyl acetate (VAc) as monomers. With this co- polymer, polymer membrane and polymer electrolyte were prepared on the basis of polyethylene membrane. Performances of the synthesized copolymer and prepared polymer membrane and electrolyte were studied with FTIR, GPC, DSC/TG, SEM and battery charging and discharging experiments. It was found from FTIR that PMMA-VAc was formed by breaking the double bonds of monomers. PMMA-VAc can be easily dis- persed in mixed carbonates to form a gel. The viscosity of the gel increases with the content of PMMA-VAc in carbonates, and the best content o