微波辐射全氟磺酸树脂催化合成柠檬酸三丁酯的研究.pdfVIP

第 31 卷第 2 期 2009 年 3 月 Vol.31 No.2 Journal of Tangshan Teachers College Mar. 2009 微波辐射全氟磺酸树脂催化合成柠檬酸三丁酯的研究 董玉环，李德玲，王雪慧 （唐山师范学院化学系，河北 唐山 063000 ） 摘 要：以柠檬酸和正丁醇为原料，废弃的全氟磺酸树脂为催化剂，在微波辐射条件下合成柠檬酸三丁酯， 对影响合成柠檬酸三丁酯的因素进行研究。结果表明：微波辐射条件下，醇酸摩尔比为 6 ∶1、催化剂用量为 0.315g 、 微波辐射时间为 40min 、微波辐射功率为 500W ，柠檬酸三丁酯的最高产率可达93.9%。该催化剂绿色环保且易于 回收，重复使用六次以上产率仍可达到90% 以上。 关键词：全氟磺酸树脂；柠檬酸三丁酯；催化合成；微波辐射 中图分类号：TQ225.24 文献标识码：A 文章编号：1009-9115(2009)02-0022-03 Study of the Perfluorosulfonic Acid Resin Catalyst for the Synthesis of Tributyl Citrate under Microwave Irradiation DONG Yu-huan, LI De-ling, WANG Xue-hui (Department of Chemistry, Tangshan Teachers College, Tangshan Hebei 063000, China) Abstract: The tributyl citrate has been synthesized by citric acid and n-butyl alcohol catalyzed by rejected perfluorosulfonic acid resin under microwave irradiation. The author has also examined the synthetic conditions with perfluorosulfonic acid resin as catalyst. Under the microwave irradiation, the result also shows that the ester yield is 93.9% under the optimum operation conditions: the molar ratio of n-butyl alcohol to lactic acid is 6:1; the amount of catalyst is 0.315g, the reaction time is 40min and power of microwave irradiation is 500W. The catalyst is easy to be recovered and can be reused for many times. After six times, the ester yield is also over 90%. Key words: perfluorosulfonic acid resin; tributyl citrate; catalytic synthesis; microwave irradiation 柠檬酸三丁酯是一种用途广泛的无毒增塑剂，可代替具 酯报道。本文采用废弃的全氟磺酸树脂作催化剂，在合成柠 有致癌作用的邻苯二甲酸酯类增塑剂。随着人们环保意识的 檬酸三丁酯中显示催化活性高，产率高，便于回收，重复使 不断增强，利用