微胶囊包覆的聚硫酸铵铝在聚氨酯中的阻燃作用.pdfVIP

J Therm Anal Calorim (2015) 120:1327–1335 DOI 10.1007/s10973-015-4425-3 Thermal degradation and flame retardancy of microencapsulated ammonium polyphosphate in rigid polyurethane foam Fubin Luo • Kun Wu • Mangeng Lu • Shibin Nie • Xiaoya Li • Xiaoxiao Guan Received: 6 November 2014 / Accepted: 10 January 2015 / Published online: 19 February 2015 ´ ´ Akademiai Kiado, Budapest, Hungary 2015 Abstract Microencapsulated ammonium polyphosphate Introduction MFAPP or VMFAPP with shell of melamine–formalde- hyde or poly (vinyl alcohol)–melamine–formaldehyde Rigid polyurethane foams (PU) are widely used in building resin was prepared by in situ polymerization, respectively. insulation and domestic appliances, due to their superior The flame-retardant performance of rigid polyurethane mechanical properties and low density [ 1, 2]. However, rigid foam (PU) containing MFAPP or VMFAPP was analyzed polyurethane foams are very combustible materials having by limiting oxygen index and UL-94 test. Thermal degra- fast flame spread and high heat release rates [3, 4]. So, it is dation behaviors of PUAPP, PUMFAPP and PUVMFAPP significant to improve flame-retardant properties of PU. were studied using TG and TG–FTIR. Above results Intumescent flame-retardant system (IFRs) that has been indicated that VMFAPP and MFAPP have better water used in flammable polymers such as PU usually contains resistance and flame retardancy compared with ammonium three active ingredients, i.e., an acid agent (e.g., ammo- polyphosphate (APP) in PU composites. Flame-retardant nium polyphosphate), a carbonization agent (e.g., polyol) properties of PUMFAPP and PUVMFAPP composites and a blow