组合电磁场、超声场对纳米碳酸钙碳化反应及结晶影响.pdfVIP

1 组合电磁场、超声场 对纳米碳酸钙碳化反应及结晶的影响 王茂森 济南高新技术创业服务中心， 山东 济南 250100 〔摘要〕以碳化反应动力学理论、分子反应动态学的碰撞理论、分子尺度上的微观混合 理论与反应结晶理论为基础，根据电磁场、超声场的有关原理探讨了组合的电磁场和超声场 效应的协同作用，可以达到提高相间相对速度，强化相间传质速率，实现良好的微观混合状 态和产生压力波动；通过电磁场的“磁聚集”提高分子间的碰撞概率，通过超声场的空化效 应增大碰撞能量两种机理达到增加有效碰撞，促进碳化反应过程动力学；电磁场的的磁化、 极化和超声场的空化效应均对碳化法制备纳米碳酸钙的碳化反应动力学及结晶动力学过程 产生积极的影响，可加速碳化反应速率，提高碳酸钙晶核的成核速率并通过抑制晶体生长或 对较大晶体的破碎作用，使晶体粒径微细化、均一化，为控制最终产品粒径在 100nm 以内 创造了条件。 〔关键词〕纳米碳酸钙；电磁场；超声场；磁聚集；碳化；结晶。 Abstracts: As a kind of important chemical materials, calcium carbonate nanoparticles is being used more and more widely in the high-tech area. The Caco3 nanoparticles can be produced by various method. Here the effects of combination of external electric field and supersonic wave on the rates of carbonation reaction and crystallization kinetics for Caco3 nanoparticles have been investigateced It was found that a strength synergistic effects between them on the acceleration of rate of carbonation reaction and nucleation of Caco3 crystalls. This may be interpreted by that the external electric field can accelerate the transfer of charged ions and the polarization of the molecules, so the rate of carbonation reaction can be accelerated. In addition, the cavitation of the supersonic wave can produce a huge instant pressure and high temperature followed with a strong shock-wave, so it can increase the nucleation rate of Caco3 crystalls and make the larger Caco3 particules broken. This two factors are all induce the size of the Caco3 particles ultafine and uniform The external electric field and supersonic wave have been applied as a factor to affect the morphology and size of Caco3 nanoparticles produced by carbonation method in the three phase systems consisting of gas / liquid / solid. The research results showed that the Caco3