温度对厨余垃圾两相厌氧消化中水解与酸化过程的影响_赵杰红.pdfVIP

第 27 卷第 8 期 环 　　境 　　科 　　学 Vol . 27 ,No . 8 2006 年 8 月 EN V IRON M EN TAL SCIEN CE Aug. ,2006 温度对厨余垃圾两相厌氧消化中水解和酸化过程的 影响 赵杰红 ,张波 ,蔡伟民 (上海交通大学环境科学与工程学院 ,上海 　200240) ( ) ( ) 摘要 :实验考查了厨余垃圾在 4 个温度 25 ℃、37 ℃、40 ℃、50 ℃ 条件下的水解率 、挥发酸 V FA 产量和速率 、乳酸产量和有机 酸的组成. 结果表明:温度对水解和酸化过程均有较大影响 ,在小于 37 ℃范围内水解率和酸化率均随温度升高而增加 ,最大的 V FA 浓度在 37 ℃下获得 ,达34 4g/ L . 超过 37 ℃,酸化率下降而水解率继续增加 ,最大水解率在 50 ℃下获得达 82 %. V FA 中以 甲酸和乙酸为主 ,并有少量丙酸和丁酸产生 , 同时乳酸浓度一直较高. 通过实验确定了厨余垃圾水解酸化过程的最优温度条 件为 37 ℃. 关键词 :厌氧 ;水解 ;酸化 ;温度 ;厨余废物 ( ) 中图分类号 :X705 　文献标识码 :A 　文章编号 :0250330 1 2006 Infl uence of Temperature on Hydrolysis and Acidogenesis of Kitchen Wastes in TwoPhase Anaerobic Digestion ZHAO J iehong , ZHAN G Bo , CA I Weimin ( School of Environmental Science Engineering ,Shanghai J iaotong University ,Shanghai 200240 ,China) Abstract :The exp eriment evaluated t he solubilization rate and V FA production rate of kitchen wastes wit h controlledtemp erature at 25 ℃, 37 ℃, 40 ℃and 50 ℃, and subsequently investigated t he lactic acid production and constituent s of individual organic acids at various temp erature levels. Result s show t hat t he increase of temp erature when below 37 ℃ may improve bot h hydrolysis and acidogenesis rates and acidogenesis rate decreases while hydrolysis rate increases above 37 ℃. The maximum V FA concentration of 34 4 g ·L - 1 was achieved at 37 ℃ and a higher hydrolysis rate of 82 % was obtained at 50 ℃. Formic and acetic acid were predominant V FA , while propionic and butyric acid took a relatively little p art . And lactic acid concentration remained relatively high . Accroding to t he exp eriment an optimum temp erature to opti