水溶性硅钢片漆de制备及新型固化剂对其性能de影响.pdfVIP

20 虞鑫海等：水溶性硅钢片漆的制备及新型固化剂对其性能的影响 绝缘材料 2015 ，48(2) 水溶性硅钢片漆的制备及新型固化剂 对其性能的影响 虞鑫海，陈晓玲，周崇园，施静文，井滋萱，李凌洁 （东华大学 应用化学系，上海 201620 ） 摘要：以水溶性环氧树脂为基体树脂，配以自制的新型环氧固化剂2,2-双[4- （2,4-二氨基苯氧基）苯基]丙烷 (BDAPPP) ，通过改变固化剂及基体树脂的配比制得水溶性硅钢片漆，并对其性能进行研究。结果表明：固化 剂的用量对水溶性硅钢片漆的综合性能具有直接的影响，当固化剂的质量分数为基体树脂的14%时，制备的 水溶性硅钢片漆表现出优异的性能，其拉伸剪切强度达38 MPa ，介电常数为3.7 ，附着性达1级，完全符合硅钢 片漆的性能要求。 关键词：环氧树脂；硅钢片漆；水溶性；制备；性能 + 中图分类号：TM215.4 2 文献标志码：A 文章编号：1009-9239（2015 ）02-0020-05 Preparation of Water-soluble Silicone Steel Sheet Varnish and Effect of Novel Curing Agent on Its Properties Yu Xinhai, Chen Xiaoling, Zhou Chongyuan, Shi Jingwen, Jing Zixuan, Li Lingjie (Department of Applied Chemistry, Donghua University, Shanghai 201620, China) Abstract: Using water-soluble epoxy resin as matrix resin, self-made 2,2-bis[4-(2,4-diaminophenoxy) phe- nyl]propane(BDAPPP) as novel curing agent, we prepared a water-soluble silicone steel sheet varnish by changing the ratio between curing agent and matrix resin, and its properties were studied. The results show that the curing agent content has direct influence on the comprehensive properties of the varnish. When the mass fraction of BDAPPP is 14% of the matrix resin, the water-soluble silicone steel sheet var- nish has excellent properties, and its tensile shear strength is 38 MPa, the dielectric constant is 3.7, and the adhesion attain grade 1, which completely meet the requirements of silicone steel sheet varnish. Key words: epoxy resin; silicone steel sheet varnish; water-soluble; preparation, property 0 引 言 研究热点。 硅钢片漆是一种用于高压电机定子铁芯的绝 目前，国内对水溶性硅钢片漆研究较多的机构 缘材料，它决定着定子铁芯的性能。随着我国电力 主要有哈尔滨大电机