四羟甲基四14二噻英四氮杂卟啉锌的合成、表征和性能.pdfVIP

第29卷第2期 中南民族大学学报(自然科学版) V01．29No．2 JournalofSouth—Central for 2010年6月 UniversityNationalities(Nat．Sci．Editioa)Jun．2010 四羟甲基四(1，4一二噻英)四氮杂卟啉锌的 合成、表征与性能 邓克俭，管亚云，王亚娟，陈连清’ (中南民族大学催化材料科学湖北省暨国家民委一教育部共建重点实验室武汉430074) 摘 型分子，初步考察了ZnPz(CHzOH—dtn)t在温和条件下的光催化性能．研究表明：羟甲基四氮杂卟啉锌有较好的活 化分子氧的能力． 关键词 四羟甲基四(1，4一二噻英)四氮杂卟啉；活化分子氧；循环伏安法；光催化降解 中图分类号0626．44文献标识码 A文章编号 1672—4321(2010)02—0015—03 and ofZinc(Ⅱ) Synthesis，CharacterizationProperties Tetrahydroxymethyl DengKejian，GuanYayun，WangYajuan，ChenLianqing’ of andMaterialsScienceoftheStateEthnicAffairs of (KeyLaboratoryCatalysis Commission＆Ministry Materials Education，Hubei of and Science，South—Central Province。CollegeChemistry University forNationalities．W11han430074．China) Abstract been Zinc(I)tetrahydroxymethyltetra(1，4-dithiin)porphyrazine intermediate of method．The synthesizedusingprepared 2，3-dicyano一5一hydroxy-methyl-1，4-dithiinbytemplate hasbeencharacterizedelemental andIR electrochemical complex by analysis．UV—Vis，XPSspectrum．The behaviorofthe was by wasestimatedfor complexinvestigatedcyclicvoltammetry．Itsphotocatalyticcapability ofa RhodamineB(RhB)undervisibleirradiation．Theresultsindicatethat degradationprobedyecompound light a to ZnPz(CH20H—dtn)‘hasabilityactivatemole