红磷母粒对ABS-IFR复合材料的协同阻燃作用有.pdfVIP

Applied Mechanics and Materials Vols. 599-601 (2014) pp 128-131 Submitted: 10.05.2014 Online available since 2014/Aug/11 at Accepted: 05.06.2014 © (2014) Trans Tech Publications, Switzerland doi:10.4028//AMM.599-601.128 Synergistic Effects of a Red Phosphorus Master Batch on a modified Intumescent Flame Retardant ABS Composites Pei-Bang Dai1,a, Yue-Qun Lu1,a, Li-Li Fan1,a, Yu-Ru He1,a 1School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, P.R. China adaipeibang@163.com Keywords ABS; red phosphorus; thermal stability; intumescent flame retardant; char layer; composites Abstract: The effects of a red phosphorus master batch (RPMB) on a modified intumescent flame retardant (MIFR) ABS composite system (ABS-MIFR) were investigated in this study. The Underwriters Laboratory Bulletin 94 (UL-94) flame retardancy rating clearly revealed the synergistic interactions of RPMB and MIFR. Thermogravimetric analysis was used to evaluate the thermal decomposition of these flame retardant composite systems. The results show that adding RPMB increased the char residue formation and the thermal stability of ABS-MIFR at high temperature. 1. Introduction ABS is a widely used engineering thermoplastic in electronic and electricity industry owing to its desirable properties such as good mechanical properties, chemical resistance and easy processing characteristics. One of the main drawbacks of ABS is its inherent flammability. Various papers have reported flame retardant ABS composites [1-11]. Superior flame retardant effectiveness can be achieved by using traditional, halog