铝管表面钝化处理的研究.pdfVIP

铝管表面钝化处理研究* 尹晓莹，满瑞林，梁永煌，赵鹏飞 （中南大学化学化工学院，湖南省 长沙市 410083 ） 摘要：本文以冰箱、冰柜蒸发器用铝管为研究对象，采用以硅烷偶联剂为主体的钝化剂进行处理。论文通 过正交设计试验和单因素实验对钝化配方及工艺进行了考察，得到最优的钝化配方为：30ml/L 的巯丙基硅 烷（MD ），3g/L 的磷酸酯，50ml/L 的乙醇，1.5g/L 的添加剂A ，调节pH=2.5 ；最优钝化工艺为：40 ℃钝化 30s ，100℃固化60min。论文对产品质量进行了测定和表征，结果表明该钝化可显著提高铝管的耐蚀性能， 质量优于铬盐钝化膜。金相显微镜对硅烷膜表面形貌分析显示，硅烷膜很好地覆盖在铝管表面，对基体覆 盖度高，且膜层致密、均匀和平整。此外，本文初步探讨了成膜和耐蚀机理。 关键词：铝管；硅烷钝化；无机添加剂；耐蚀性 中图分类号：TQ 028.8 文献标识码：A Study on the Passivation Treatment to the Surface of Aluminum Tube Yin xiaoying, Man ruilin, Liang yonghuang, Zhao Pengfei (College of Chemistry and Chemical Engineering, Central South University, Hunan, Changsha 410083, China) Abstract ：In this paper, the study on the passivation of new technology for the refrigerator and freezer evaporator aluminum tube was carried out. Organic silane was used as the main film-forming agent to treat aluminum surface. The optimal passivation formula and passivation technology that were 30ml/L mercapto-propyl silane (MD), 3g/L phosphate, 50ml/L ethanol, pH = 2.5, 1.5g/L additive A and passivation 20s at 40 ℃,curing 90min at 100℃ were obtained by orthogonal experiment and single factor experiments. The product quality has been tested and the results showed that the passivation could significantly improve the corrosion resistance of aluminum tube, superior the quality of chromate passivation. Metallographic microscope was used to analysis the morphology of silane membrane surface, and the result showed that the silane membrane covered well on the aluminum tube surface, while the membrane layer were of high coverage, uniform and dense. In addition, the passivation film forming and corrosion mechanism was preliminary studied. Key words ：Aluminum tubes; silane passivation; inorganic a