AlN_碳掺杂氮化硼纳米管复相陶瓷的制备及性能.pdf

第38 卷第8 期 硅 酸 盐 学 报 Vol. 38 ，No. 8 2 0 1 0 年 8 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY August ，2010 AlN/碳掺杂氮化硼纳米管复相陶瓷的制备及性能 李戴利戴梁海龙戴张久兴 (北京工业大学材料科学与工程学院，新型功能材料教育部重点实验室，北京 100124) 摘 要：将 1%～10%(体积分数)碳掺杂氮化硼纳米管(carbon-doped boron nitride nanotubes，BCN-nt)引入到纳米AlN 中，采用放电等离子烧 结得到致密的AlN/BCN-nt 复相陶瓷。结果表明：适当提高烧结温度能使AlN 晶粒充分长大，提高AlN 晶粒完整性并有效去除结构中的氧 杂质，因而显著改善了引入BCN-nt 对热导率的劣化。在Kα波段(26.5～40.0 GHz)，随BCN-nt 含量的增加，材料的介电常数实部和虚部都呈 现逐渐增大的趋势，损耗因子也逐渐增加。提高烧结温度对介电常数影响不大，而过高的温度使介电常数虚部明显下降。适当的BCN-nt 含 量和烧结温度能够在提供稳定的介电损耗同时兼顾较高的热导率。 关键词：氮化铝；放电等离子烧结；热导率；介电性能 中图分类号：TM25 文献标志码：A 文章编号：0454–5648(2010)08–1440–05 FABRICATION AND PROPERTIES OF AlN/CARBON-DOPED BORON NITRIDE NANOTUBES COMPOSITES LI Yongli ，LIANG Hailong ，ZHANG Jiuxing (Key Laboratory of Advanced Functional Materials, Ministry of Education of China, School of Materials Science Engineering, Beijing University of Technology, Beijing 100124, China) Abstract: Highly dense AlN/BCN-nt composites with 1%–10% (volume fraction) carbon-doped boron nitride nanotubes (BCN-nt) were fabricated by spark plasma sintering. The results indicate that even though the degradation with incorporation of BCN-nt into AlN, the thermal conductivity of sintered AlN/BCN-nt composites is evidently improved with the growth of AlN grains and the elimination of oxide contamination by increasing sintering temperature. Both the real part and imaginary part of the composites of Ka-Band (26.5–40.0 GHz) increase with the increase of BCN-nt content, in which the increase of imaginary part is more than that of real part, resulting in an increase of loss factor. Increasing sintering temperature does not have o