三聚氰胺甲醛树脂_MF_改性淀粉胶粘剂的研究与应用.pdfVIP

( MF) 29 三聚氰胺甲醛树脂( MF) 改性淀粉胶粘剂的研究与应用 黄智奇, 梁祝贺, 张雷娜, 吕建平 (, 230009) : 以淀粉为主要原料, 制备三聚氰胺甲醛树脂( MF) ,改 淀粉胶粘剂用红外光谱表征改 的每 个阶段, 验证其改 机理X- ray 衍射说明了MF 对淀粉的结晶度影响不大,M F 主要是交联改 的淀粉的无定型区; 扫描电镜显示M F 对淀粉颗粒形成塑化, 改变了淀粉颗粒的表面形貌, 通过交联形成网状结构结果表明,M F 改 提高了淀粉胶粘剂的耐水 与稳定 , 常温下保存7 d 后,其耐水时间粘度分别为96 h 和500 mPa s : 淀粉; 三聚氰胺甲醛树脂; 胶粘剂; 瓦楞纸 : TB484; T Q321.2 : : 1001- 3563( 2011)01- 0029- 04 Development and Application of Starch Adhesive Modified by Melamine Formalde hyde Resin H UA N G Zhiqi , L I A N G Zhuhe, ZH A N G L eina , L V J ianp ing (Hefei University of Technology, Hefei 230009, China) Abstract: Modified starch adhesive was prepared by melamine formaldehyde resin ( MF) . Modification was characterized by IR at each stage and modification mechanism was verified. Xray diffraction showed that MF can crosslink amorphous area, but hardly effects on the degree of crystallinity of starch. SEM analysis showed that MF can plasticize starch granules, change surface morphology of starch granules and form network struc ture by crosslinking. The results showed that the MF improves the water resistance and stability of starch ad hesive. t room temperature the modified starch adhesive can keep for 7 days, and its water resistance is 96 h and its viscosity is 500 mPa s. Key words: starch; melamine formaldehyde resin; adhesive; corrugated paper , , , , , ,(MF) , , ,, , , , [ 1- 2] , , SEM Xray , , , , 1 , [3] ,, 1. 1 ,, : ,, ( PS) ;,, : : (