褐煤自燃机理及阻化剂防自燃技术进展-2016论文阅读-下载.pdfVIP

中国科技论文在线 褐煤自燃机理及阻化剂防自燃技术进展 1 1 1 2* 张静 ，吴国光 ，孟献梁 ，孙奇 （1. 中国矿业大学 化工学院，江苏 徐州 221008； 5 2. 郑州瑞茂通供应链有限公司，郑州450000） 摘要：我国褐煤资源储量丰富，但褐煤，尤其提质后褐煤极易发生自燃。本文从褐煤的化学 结构和孔隙特征等角度分析了其自燃机理，综述了卤盐吸水液、铵盐阻化液、氢氧化钙阻化 液、硅凝胶和高聚物阻化剂等常用防自燃阻化剂，对它们的作用原理和阻化效果进行了详细 阐述，并指出了这些阻化剂存在的局限性，在此基础上提出了阻化剂防自燃技术的发展方向。 10 关键词：褐煤；自燃机理；阻化剂 中图分类号：TD75+2 The Lignite Spontaneous Combustion Mechanism and the Progress of Inhibitors Technology 1 1 1 2 15 ZHANG Jing , WU Guoguang , MENG Xianliang , SUN Qi (1. School of Chemical Engineering and Technology, China University of Mining Technology, JiangSu XuZhou 221008; 2. Zhengzhou Ruimaotong Supply Chain Limited Company, ZhengZhou 450000) Abstract: Our country is abundant in lignite resources. But spontaneous combustion occurs easily 20 on lignite, especially dry lignite. The spontaneous combustion mechanism of lignite was analyzed from its chemical structure and pore characteristics in this paper. Some common inhibitors, such as halogeno salt inhibitors, ammonium salt inhibitors, calcium hydroxide inhibitor, silicone gel and polymer inhibitors, were described about their action principles, effects and shortcomings. And based on this, the trends of the new technology and new materials of inhibitors are 25 prospected. Keywords: lignite; spontaneous combustion mechanism; inhibitors