包埋-化学气相沉积两步法制备ZrC涂层的结构与抗烧蚀性能.pdfVIP

第18 卷第6 期 粉末冶金材料科学与工程 2013 年12 月 Vol.18 No.6 Materials Science and Engineering of Powder Metallurgy Dec. 2013 包埋−化学气相沉积两步法制备ZrC 涂层的 结构与抗烧蚀性能 吴 敏，李国栋，熊 翔，杨钢宜 ( 中南大学 粉末冶金国家重点实验室，长沙410083) 摘 要：采用先包埋、然后化学气相沉积(CVD)的复合工艺，在石墨材料表面制备ZrC 涂层，并对其进行氧乙炔 焰烧蚀试验。借助X 射线衍射(XRD)和扫描电镜(SEM)分析烧蚀前后涂层的微观组织形貌及相组成，研究涂层的 抗烧蚀机理。结果表明：包埋−CVD 两步法制备的ZrC 涂层，包埋层具有双层结构，外层多孔、内层致密；CVD 层表面呈凸胞状形貌，为柱状晶结构；包埋多孔层与 CVD 层相互嵌入，形成机械互锁结构，增强了涂层间的界 面结合强度。30 s 氧乙炔焰烧蚀试验表明：ZrC 涂层具有很好的结构稳定性和良好的抗热震性能；烧蚀产物为单 斜型ZrO ，质量烧蚀率和线烧蚀率分别为1.50×10−3 g/s 和0.47×10−3 mm/s ，涂层具有良好的高温抗烧蚀性能和抗 2 冲刷性能。 关键词：包埋；化学气相沉积；ZrC 涂层；显微结构；抗烧蚀性能 中图分类号：TB332 文献标识码：A 文章编号：1673-0224(20 13)6-827-07 Microstructure and ablation properties of ZrC coating prepared by two-step technique of pack cementation and CVD WU Min, LI Guo-dong, XIONG Xiang, YANG Gang-yi (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: The ZrC coating was prepared by a two-step technique of pack cementation and chemical vapor deposition (CVD) processes, and investigated by oxyacetylene torch flame test. The surface morphology and phase composition of the coating before and after ablation were studied by SEM and XRD analysis, and then the ablation mechanisms were investigated. The results show that in the as-prepared coating, the coating prepared by pack cementation method has a double structure with the outer porous layer and the inner dense layer; the CVD layer forms columnar crystal structure with smooth arch surface; the porous layer and the CVD layer are m