生产酸性管线用坯中的偏析的定量检测.pdfVIP

生产酸性管线用坯中的偏析的定量检测 Bernhard Hoh (俄勒冈钢铁厂) 摘 要 偏析是生产抗 HIC 钢所要克服的主要问题。一次初生偏析是凝固过程中固有的、不 可避免的特征。固液相之间的组成关系决定了微观偏析，并受钢的化学成分和冷却速度的影 响。当微观偏析的液体通过液体流动而聚集和转移，这就导致了宏观偏析的发生。俄勒冈钢 铁厂使用计算机辅助微观分析仪对压力铸造板坯进行系统地检测。微探针测量了试样的一大 片区域的元素浓度，基于浓度的概率分布的统计评定是定量分析的基础。通过它，就可以得 到诸如偏析因子、最大浓度之类的特征参数。 本文讨论碳对偏析结构及锰的偏析特征的影响，并与连铸坯的偏析结果进行对比。 关键词 偏析 定量检测 抗 HIC QUANTITATIVE EXAMINATION OF SEGREGATION IN SLABS FOR THE PRODUCTION OF SOUR SERVICE LINEPIPE Bernhard Hoh OREGON STEEL MILLS Abstract Segregation is a major problem to be overcome by producers of HIC resistant steels. Primary segregation is an inherent and unavoidable feature of the solidification process. The constitutive relationship between solid and liquid stage determines microsegregation and it is influenced by the chemical composition of the steel and its cooling rate. Macrosegregation occurs when microsegregated liquids collect and shift through liquid flow. OREGON STEEL MILLS has conducted systematic measurements in pressure-cast slabs using a computer assisted micro analyzer. This microphrobe measures element concentrations over a large area of the specimen. A statistical evaluation based on the frequency distribution of the concentrations forms the basis of a quantitative analysis. From this, characteristic parameters such as the segregation factor and maximum concentration can be derived. This paper discusses the influence of carbon on segregation structure and on segregation properties of manganese, and compares the results with those of continuously cast slabs. Key Words: Segregation Quantitative examination HIC resistant 1、介绍 近几年来，在抗氢致裂纹（HIC ）钢管中， DSAW 管所占的比例稳步提高。采用 NACE TM0284 标准来检测材料抗酸性气体的能力。许多规范有更严格的要求，规定在 pH 值为 3 的酸性环境中使用NACE TM0177 检测标准。 氢致裂纹（