Fe-MoAl_2O_3催化剂催化分解甲烷制备碳纳米管温度对碳管结构的影响.pdf

第24卷第4期 新型炭材料 V01．24No．4 NEW MATERIALS Dec．2009 2009年12月 CARBON Article ID：1007-8827(2009)04-0307-07 ofcarbon the ofmethane Growth nanotubes by catalyticdecomposition over of ontubestructure catalyst：effecttemperature Fe-Mo／A1203 SONG Jin—lin91’2，WANGLil·2，FENGShou—ail，ZHAOJiang．hon91，ZHUZhen．pin91 (1．State研LaboratoryofCoalConversion，InstituteofCoalChemistry，ChineseAcademyof-g,nc日，Taiyuan030001，China； 2．Graduate UniversityofChineseAcademyofSciences。aeijing100049．Ch／na) Abstract：nleeffectsof time。andflowrateonthestructureofcarbon temperature．reaction studied chemical ofmethaneoveran showthatthetem． usingcatalytic vapordeposition Fe．Mo／—山0，catalyst．Results isa to walIthicknessofthe tothe multi- controlthe CNTs．Low leads formationof peraturekeyparameter temperature walledcarbonnanotubes(MWCNTs)withwallthicknessof2_7 isinfavorofthe nnl．Relativelyhightemperature ofdouble—walledcarbon the of nanotubes(DWCNTs)，whereas growth hightemperaturepromotesgenerationsingle— walledcarbon furtherincrease in ofMWCNTswith nanotubes(SWCNTs)．Aof resultsthe a temperature generation wallthicknessof3．15mnand carbon