制备高碳醇Cu_Fe系催化剂的比表面积_孔结构和孔径分布.pdfVIP

13 3 Vol. 13, No. 3 1999 6 JOURNAL OF MOLECULAR CAT ALYSIS (CHINA) Jun. 1999 : 1101 3555 ( 1999) 03 0199 06 - Cu Fe 刘寿长, 关新新 陈诵英 ( , 450052) ( , 310028) : ASAP 2000 , Cu Fe . , , ; , . . pH , . , , (4 V/ A , BET ) Cu Fe . , . : ; Cu Fe ; BET ; : O643. 38: A 1 : [ 1] . : ASAP 2000 ( ) . , . BET . ( single condensation point p /p 0 = 0. 99) . , 4 V/A ( V , A BET ) (pore size) . 2 2. 1 1 Cu Fe BET . 1, , . Cu Fe [ 2] XRD Mossbauer , , ; , . Cu Fe . 480 , , , . , ( 10 nm) , . BET . , . Cu Fe1618 : 1998 06 29; : 1998 09 02. : , , 49, , . 200 13 , , [ 3] . , , . , [ 4] , ( Mg( OH) 2) . , . . 1 Cu Fe BET Table 1 BET surface area t otal pore volume pore size and pore size distribution, , of samples calcined at different temperatures Calcination BET surface T otal pore M ost probable Yield of high No. temperature area volume Pore size pore diameter alcohols ( ) ( 2/ ) ( 3/ ) ( ) ( ) ( %) m g cm g nm nm 1 320 107.5 0. 355 13. 19 1820 52. 6 2 400 84. 1 0. 363 17.28 1825 58. 7 3 480 36. 1 0.294 32.58 2732 68. 5 4 560 19.4 0. 123 25.27 4044 59. 4 * No. 1No.4 catalyst s have the same