均相CoPMS系统降解吡虫啉的影响因素及降解途径研究.pdf

第28卷第12期 环 境 科 学 V01．28．No．12 2007年12月 Dec．．2007 ENVIRONMENTALSCIENCE 研究 陈晓呖1’2，陈景文H，杨萍1，乔显亮1 (1．大连理工大学环境科学与工程系，大连116024；2．浙江省农科院环境资源与土壤肥料研究所，杭卅l310021) 解的中间产物，得到了6一氯烟酸和6一氯烟酰胺2种主要的中间产物，并由此推测其可能的降解途径． 关键词：高级氧化技术(AOTs)；硫酸自由基；无机离子；降解机理；废水处理；毗虫啉 中图分类号：X703文献标识码：A文章编号：0250—3301(2(脚)12—2816—05 InnuentialFactorsand of DegradationPathwayImidadop订dby Co／PMSSvstem CHEN Xiao—yang“2，CHENJing-wenl，YANGPin91，QIAOXian—lian91 0f Dalian 0f Dalian 0f Environmen试Scienceand “6024，Chi加；2．Institute (1．Depanmenf Technology， Univers毋Technolog)r， and of Envimnment，Resource，soilFenilizer，zhejiangAcademyAgriculturaJSciences，Hangzhou310021，China) of isoneofnoveladvancedoxidation Abstract：CobaJtous-mediated decompositionpemxymonosu瓶te(Co，PMS)system whichleadstothef0珊ationof in 0fPMS andvarious verystrongoxidizingspeciesaqueousphase．Efrects the of inducedCo／PMS wa8 as ino唱anicanions(H2P0f，HC0f，N0f，Cl一)ondegmdationImidaclopridby systeminvesti98tedemphasis． The kineticsof f0Uowed first—orderkineticsandreactionratesrelatedt0PMSand degradation imidaclopridpseudo rates the were of reactionincreasedwith other constaIlt．However，thedecrease increasing[PMS]and[c∥+]whenparameters wasover20．The of had of rateswasfoundwhenthemolarratioofPMSversus e饪bcts e饪bctonthe