低合金高强度钢在深海静水压力环境中腐蚀行为研究.pdfVIP

The 6th China Corrosion Conference A Study on Corrosion Behaviour of a High Strength Low Alloy Steel under Hydrostatic Pressure in Deep Ocean * Haijing SUN, Li LIU, Ying LI , Fuhui WANG State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang, China Email: liying@imr.ac.cn, 62, Wencui Road, Shenhe Borough, Shenyang, Liaoning, 110016 Abstract: The corrosion behaviour of a high strength low alloy steel (HSLA steel) under hydrostatic pressure in deep ocean was investigated by weight loss measurement, capacitance measurement and electrochemical impedance spectroscopy (EIS). The influences involved into three typical stages: during 1-5 days’ immersion, corrosion at 35 atm was accelerated due to the increase of Cl- adsorption; during 5-10 days’ immersion, corro- sion rate was lower, because the surface of steel was covered by corrosion products completely at 35 atm but partly at 1 atm; after 10 days’ immersion, hydrostatic pressure promoted corrosion again partly attributed to the expedite transportation of corrosive particles. Keywords: deep ocean; hydrostatic pressure; HSLA steel; EIS 低合金高强度钢在深海静水压力环境中腐蚀行为的研究 孙海静，刘莉，李瑛* ，王福会 中国科学院金属研究所金属腐蚀与防护国家重点实验室，沈阳，中国，110016 Email: liying@imr.ac.cn ，辽宁省沈阳市沈河区文萃路62 号 摘 要：本论文采用静态挂片失重、电容- 电位曲线和电化学阻抗（EIS ）等方法研究了对一种低合金 高强度钢（HSLA 钢）在35 atm 静水压力下的腐蚀行为。结果表明，在不同的浸泡阶段静水压力对该 材料腐蚀行为的影响分别为：浸泡 1-5 天时，静水压力通过增加Cl-在钢表面吸附量加速材料的腐蚀； 浸泡5-10 天时，由于35 atm 下产物膜完全覆盖样品表面，而1 atm 下只有部分覆盖，从而导致高静水 压下腐蚀速度反而略低；浸泡 10 天之后，1 atm 和35 atm 下材料表面均被产物膜完全覆盖，静水压力 则通过加速侵蚀性粒子的传输，再次加速材料的腐蚀。 关键词：深海；静水压力；HSLA 钢；电化学阻抗谱