《现代有机合成新技术》（第2版）.pdf

分 析 化 学 第42卷 912 9 YUAN Zhuo-Bin,LV Yuan-Qi,ZHANGYu-Ping,YIN Ming. MetallurgicalAnalysis,2003,23(2):24-30 袁倬斌, 吕元琦,张裕平,尹 明. 冶金分析,2003,23(2):24-30 10 CAI Shu-Xing,HUANG Chao. Analysis of Precise Metals (1). Beijing:Melellurgical Industry Press. 1984:86 蔡树型,黄 超. 贵金属分析(第一版),北京:冶金工业出版社,1984:86 Determination of Ruthenium,Rhodium,Palladium,Iridium and Platinum in Copper-Nickel Sulfide Ores by Bismuth-Antimony Fire Assay * LI Ke-Ji ,LIU Shu-Jun,SHAO Kun (Institute of Multipurpose Utilization of MineralResources ChineseAcademy of Geological Sciences,Chengdu610041,China) Abstract A bismuth-antimonyfireassay methodforthepreconcentrationof ruthenium,rhodium,palladium, iridium and platinum in copper-nickel sulfide ores was developed. 40.0 g bismuth trioxide,25.0 g boric acid,10.0 gsodiumcarbonateand1.00 gstarchweremixedwith 10.0 gsampleina120 mLporcelainbowl, which wasputinafurnaceat850 ℃. After20 minthetemperaturewasraisedto 1000 ℃ andheldforanother 40 min,and then the bowl was taken out,with the slag poured,which left the bismuth button to air cooling. A two-step cupellationprocedurewasdeveloped. Duringthefirst step,thebismuth buttonwascupellated in a magnesia cupel until its diameter reached 5 mm or so,then it was transferred to a crucible cover containing 20 g melting antimony and kept cupellating,at last a bead with a diameter of 1mm was obtained. The bead was microwave-digested,after cooling down to room temperature,the solvent of which was transferred to a volumetric flask and diluted to 10 ml with water. Pt and Pd were analyzed by inductively coupled plasma- 99 103 191 atomic emission spectrometry (ICP-AES),while Ru, Rh, Ir were analyz