催化氧化合成己二酸的清洁方法.pdfVIP

21 4 化 学 进 展 Vol. 21 No. 4 2009 4 PROGRESS IN CHEMISTRY Apr. , 2009 催化氧化合成己二酸的清洁方法* 任水英 解正峰 谢晓鹏 秦高飞 王吉德* * ( 新疆大学石油天然气精细化工教育部 点实验室 乌鲁木齐830046) 己二酸是一种非常 要的有机合成中间体, 由于传统生产工艺的局限性, 其绿色合成方法备受 研究者的关注本文综述了近年来用H O O 或O 作为清洁氧化剂, 以环己烯环己酮环己醇或其混合物 2 2 2 3 为原料, 催化氧化合成己二酸清洁方法的研究进展, 点介绍了含钨化合物- 双氧水体系的催化氧化法, 也概 述了几种新的己二酸合成方法, 并从溶剂产率后处理等方面探讨了各种方法的优缺点在这些方法中, 负 载催化剂- 双氧水体系将是未来工业化的最佳选择之 一 己二酸 催化氧化 双氧水 氧气 清洁氧化 : O62316; O64313; TQ426 : A : 1005-281X( 2009) 04-0663-09 Environmenta-l Friendly Synthesis of Adipic Acid by Catalytic Oxidation * * Ren Shuiy ing Xie Zhengf eng Xie X iaop eng Qin Gaof ei Wang Jide ( Key Laboratory of Oil Gas Fine Chemicals, Ministry of Education, Xinjiang University, Urumqi 830046, China) Abstract Adipic acid is a most important organic synthetic intermediate, and much attention has been paid for its green synthesis process because of disadvantages in current technology. In this paper, recent developments on catalytic o idation systems of environmental-friendly synthesis of adipic acid are reviewed, in which hydrogen pero ide, o ygen or ozone is used as clean o idant and cyclohe ene, cyclohe one andPor cyclohe anol as substrate. The focus is especially on the catalytic system of tungstate-H O , and several other new synthetic methods of adipic acid are also summarized. At 2 2 the same time, advantages and disadvantages of each cata