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Improved photocatalytic activity of Sn4+-doped and undoped TiO2外文翻译.pdf

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Applied Catalysis A: General 319 (2007) 230–236 /locate/apcata Improved photocatalytic activity of Sn4+-doped and undoped TiO2 thin ﬁlm coated stainless steel under UV- and VIS-irradiation Hikmet Sayılkan ˙ ¨ ¨ Inonu University, Faculty of Education, Department of Science, 44289 Malatya, Turkey Received 20 July 2006; received in revised form 13 November 2006; accepted 10 December 2006 Available online 27 December 2006 Abstract TiO2 can be used as a photocatalyst because of its semiconductor property. If TiO2 is doped with transition metal ions, its electronic properties are modiﬁed. In this work, nanosized Sn4+-doped and undoped TiO (TiO –Sn4+ and TiO ) particles have been synthesized without organic solvent 2 2 2 4+ n by hydrothermal process at low temperature. Nano-TiO particulates having a doping ratio of about 5 [Sn /Ti(OBu ) ; mol/mol%] allowed to coat 2 4 the stainless steel substrate by spin-coating technique. The particles and the ﬁlms were characterized by XRD, SEM, BET and UV/VIS/NIR techniques. The photocatalytic performance of the ﬁlms were tested for degradation of Malachite Green dy