溶胶-凝胶法制备LiFePO4粉体及其电化学性能研究.pdf

Hot WorkingTechnology2013，V01．42，No．10 溶胶一凝胶法制备LiFeP04粉体及其 电化学性能研究 吴朝阳。赵胜利，孙为 (河南科技大学材料学院，河南洛阳471003) 摘要：通过溶胶一凝胶法并结合热处理工艺制备LiFeP04粉体，采用XRD、SEM及恒电流充放电技术等方法，研 究了煅烧时问对LiFePO。粉体结构、形貌及电化学性能的影响。结果表明：以聚丙烯酸(PAA)、硝酸铁、硝酸锂和磷酸二 氢铵为原料。在一定温度下合成了稳定的溶胶和凝胶，经650℃煅烧得到LiFeP04粉体。随着煅烧时间的延长，粉体颗 粒逐渐增大，晶型趋于完整；煅烧16h获得的LiFeP04颗粒大小均匀，晶型完整且没有明显团聚现象。1C倍率下首次放 比电容量达到140 mAh／g，经100次循环后仍高于130mAh／g，容量保持率高达93％，表现出良好的充放电稳定性。 关键词：LiFeP04；结构；溶胶一凝胶；电化学性能 中图分类号：TB383 文献标识码：A 文章编号：1001．3814(2013)10-0060—03 andElectrochemicalofLiFeP04 Preparation Properties Powder Method PreparedbySol—gel WU W戗 Zhaoyang，ZHAO Shengli，SUN ofMaterials (School ScienceEngineering，HenanUniversityofScienceTechnology,Luoyang471003，China) was and treatment influencesof timeon Abstract：LiFeP04powder synthesizedbysol-gelheating process．The sintering the andelectrochemical were and microstructure，morphologyperformanceexploredbyXRD，SEMgalvanostatic resultsshowthatthestablesoland were and inwater NH4H2P04 charge-discharge．111e gel preparedbyPAA，FeN03，LiN03 solution．TheCallbeobtainedunder at650℃．Withtheincreaseofcalcination LiFeP04 time，LiFeP04 sintering particle becomesandthe structureismore treatmentat650℃for larger crystal in