聚羧酸系减水剂大单体PEGMAA的制备.pdfVIP

29 6 硅 酸 盐 通 报 Vo l. 29 N o. 6 2010 12 BU LLET IN OF THE CH IN ESE CERAM IC SOC IETY D ecember 20 10 PEGMAA 1 1 2 2 1 陈小平 周忠群 申迎华 马玉刚 1. 525000; 2. 030024 : : 3. 51. 0 3% 1% 90 6 h 99. 1% IR : ; ; ; : TQ325 : A : 2010 0614 9205 Synthesis ofM acrom er PEGMAA for Polycarboxylate Superplasticizer 1 1, 2 2 1 CHEN X iaop ing , ZHOU Zhong qun , SHEN Ying hua , MA Yugang 1. Institute of Chem ical Eng ineering G uangdong U n iv ersity of P etrochem ical T echnology M aom ing 525000 Ch ina; 2. Col lege of Chem istry and Ch em ical Engineering T aiyuan U n iv ers ity of T echno logy T aiyuan 030024 Ch ina Abstract: M ethacrylate po lyg lyco l m onoester w as synthesized by conden sation of po lye thylene g lycol and m eth acry lic ac id w ith to luene as the w a ter ab sorbent to lu ene4sulfon ic ac id as the catalyst and hydroqu inone as the inh ib itor. The optmi a l condition o f esterificat ion w as studied by the design th at the m o lar rate o f acry lic ac id to PEG w as 3. 51. 0 the reaction temp erature w as 90 the reaction t mi e is 6 h the am ount o f catalyst is 3% according to the m ass o f PEG the am ount of inh ib ito r is 1% according to the m ass ofMAA the rate of esterif ication up to 99. 1% . T he stru cture o f the PEGA w as ch aracterized by FT IR and the rate o f esterification. K ey words: m ethacrylic ac id; po lyethy lene g lyco l; m ethacrylate po lyg lyco l m onoester; esterificat ion 1 引 言 [ 13] [ 46] PEG MAA : 1964 . . Em ail: chenxp647@ s ina. com 6 : PEGM AA 149 3 2 试 验 2. ; PEG 1000 ; ; ; 2. 2 HH S2S ; H J5 ; Bruker T ensor FTIR B ruker 2. 3 500 mL PEG 1000 1% ~ 2% MAA 60 ~ 70 1% ~ 3% PEG 85~ 90 30 ~ 60 m in 6 h 2. 4 2. 4. 1 Bruker Bruker T en sor FT IR K Br 2. 4. 2 : OH /OH M 0. 5 g 25 mL 2~ 3 0. 1 m o l/LN aOH [ 7 ] N aOH : M V N - /2N 2 1 10000m N ; 1 N ; 2 M g ; m g ; VN aOH mL 3 结果与讨论 3. 3. 1. 1 1 1 3. 5 99. 1% 3. 5