八面体中Ni-%272%2b-离子的局部结构与自旋哈密顿参量研究.pdf

ABSTRACT ABSTRACT with Crystals transition-metalionshaveattractedextensiveattentionof doped to researchersduethefundamentaland practicalsignificance．Electronparamagnetic auseful to defectstructuresandelectronine resonance(EPR)istechniquestudy fortransition-metalionsin datahavebeen properties crystals，andmany experimental EPRstudies．EPR are reportedbyprevious results described experimentalusually by the Hamiltonian Dand factors． spin parameters，e．g．，zero—fieldsplittings E，g Theoreticalofthese call reliableinformationaboutlocal analyses parametersprovide structuresaroundthetransition-metalionswhichis tounderstandthe and helpful optical ofthesematerials． magneticproperties Asall the transition-metal been importantsystemamong group，Ni2+(3d8)has duetothe intunablesolidstatelaser extensivelyinvestigatedpromisingapplications andthe in structure ofthis uniquespectroscopicpropertiescrystals．Tostudy properties EPR havebeen onvarious inthese ion,the crystals experimentsperformed Nr十doped the Hamiltonian were decades,and spin parameters theoretical totheseHamiltonianwere interpretationsspiIl parametersunadequate，which also