萃取分离低浓度DMF含盐废水的液液平衡.pdfVIP

( ) 2011 2 ACT A PET ROLEI SINICA ( PET ROLEU M PROCE SSING SECTION) 27 1 : 1001-8719(2011) 01-0123-07 DMF - 方 静, 李春利, 王洪海, 刘继东 ( , 300130) : -, 293. 15 K, Na SO 01% 3% 5% 7% 2 4 , N, N-( DMF), , DMF NRTL , , -, 7. 15% , 1.46% , NRTL - , DMF : N , N-( DM F) ; ; ; -; NRT L : T E624. 9 : A doi: 10. 3969/j . issn. 1001-8719. 2011. 01.021 Liquid-Liquid Equilibriumfor Saliniferous Wastewater Containing Low Concentration of DMF in Extraction Process FANG Jing, LI Chunli, WANG Honghai, LIU Ji ong (S chool of Chemical E ngineer ing , H ebei Univ ersity of T echnolog y , T ianj in 300130, China) Abstract: Liqui -liqui equilibrium ata for the saliniferous system of N , N- imethyl formami e ( DM F)-w ater-chloroform w ith the Na2 SO4 mass fraction of 0, 1%, 3%, 5% , 7% , respectively, w ere etermine by using equilibrium kettle un er atmospheric pressure an 293. 15 K. T he experimental ata show e that the partition coefficient of DMF w as increase w ith the increase of salt concentration. NRT L mo el w as use to correlate the liqui -liqui equilibrium ata of the system, an binary interaction parameters w hich exhibite linear change w ith the increase of salt w ere obtaine . T he pre icte ata calculate by using the regresse parameters show e that the experimental ata w ere successfully correlate w ith NRTL mo el. T he relative root mean square eviations betw een calculate an experimental values w ere less than 7. 15% an the absolute mean eviations w ere less than 1. 46%, meaning that the thermo ynamic ata an NRT L mo el w ere useable f