表面改性浸渍树脂吸附铟和铅的研究.pdfVIP

表面改性浸渍树脂吸附铟和铅的研究 摘要 本文以表面活性剂对AB．8大孔树脂进行表面改性，制备改性P204和 脱附性能，进行热力学和动力学分析。主要研究内容和结果如下： 基三甲基溴化铵】、OP一10【壬基酚聚氧乙烯(10)醚】进行预处理(表面改性) 后，萃取剂P507和P204在树脂上的负载量均有了提高，提高顺序为： 正相关性； 别为32．47 mg·g-1和27．40 AH=5．28 kJ·mol～，AG(303K)=．2．18kJ·tool～，AS=24．61J-molI-K-1： K)=一1．18kJ·mol～， kJ·mol～，AG(303 Pb(II)的吸附热力学参数为：AH=5．31 AS=21．44J．molq．K一： 率的主要控制步骤是表面液膜扩散； 于Pb(Ⅱ)的含量低、而且存在大量钙、镁等杂质离子，对吸附干扰严重。 关键词：浸渍树脂表面活性剂铟铅吸附热力学吸附动力学磷 矿石 n 咖STUDYOFADSOI之PTIONOFSURFACEMODIFIED IM田REGNATEDRESINFORINDIUMANDLEAD ABSTRACT Twokindsofsurfactant-modified resinwhich impregnatedmacroporous loadedP507andP204 were modified respectivelyprepared．Theseimpregnated resinswereusedto indiumand and fits adsorb static lead，the dynamicadsorption wellas were desorptioninvestigated．Meanwhile，theadsorptive andkinetic were contentsandresultsareas propertiesanalysingd．Theprimary follows： WhenAB一8 resinWas macroporouspretreatmentbyusingSDS[1auryl sodium ammonium OP-10 sulfate]，CTAB[hexadecyltrimethylbromide】and [polyethyleneglycol(10)nonylphenylether]respectively,theloadingcapacity of P507andP204intheresinincreasedintheorder：CTAB extractingagent SDSOP一1 of In(III)andPb(II)onto 0；accordingly,theadsorptivecapacity resinincreasedalsointhesame themshoweda impregnated