碳氢键活化%2f碳氢键官能团化在串联反应以及其构建C-C、C-N、C-O键中的应用.pdf

碳氢键活化%2f碳氢键官能团化在串联反应以及其构建C-C、C-N、C-O键中的应用.pdf

Abstract………………………………………………………………………………II withwerewerewithwerewouldWasWasAbstractmethodmoleculesmakemetaluseUllmannuseuseusebeenbeenbondbondsbestbenzimidazolesusedbebondasanaturenewrecentC—HhasGreenThisbondresearchnewC—HC.Hnewreactions.C—HnewreactantresearchC-HC-HC—Hreactionreaction.CulC-HC--HC··0ononouroronereactionreactionreactions.BasedofandandattentionaboutandactivationasweasandactivationadditionSeriesandasofofofofofofofofofofofofofofofandactivationactivationandandandactivationconstructconstructconstruct2-disubstitudedtototothethetofunctionalizationforfromfromfocusedfunctionalizationfourfunetionalizationfromfromandabstractedadditionanddemandchemicalchemicalcascadecollectedcascadecascadecombinedchloridederivates.constructedfunctionalizationthethethethisthethethetothethethethethetothethetothethethethecascadecomestartstructureconstructcollectcombinedinininininintramolecularinintramolecularininindoleits CROSSbondbetweenaC-0viaandandoxime.11Iisochroman +Ph4SnSchemeScheme1.11-29@ RR+SchemeSchemeS1-31-41-6S MSchemeSchemeSchemeSchemeI-8I-9l-71—10 AcDCE8hDioxanePh.Ir.LOn080VNSchemeSchemeSchemeSthemel-13l-141-111-12 NHOMclROOarmSchemeSthemeSchemeScheme2011~1100Cl一15l-16l一171-18 KH2P04.t-AmOHOSchemeSchemeSchemeSchemel-21l—221-191-20 SchemeSthemeSchetneSehemel-241-231-251-26 SchemeSchemeSchemel-291-281.30 PhRuCl3ROOR202R!SchemeSchemeIl-3l1-321-331.34 PhR2+OR2oH0Schoree1-361-371.38 n0R3RlooSchemeSchemeSchemel-4l1.391-40 SchemeSchemeSchem-45 k?SchemeSchcmcScheme1-48l-471-49 CuCIOOOOOSthemeSchemeSchemeStheme1.501.511-521.53 SchcmcSchemeSchemeScheme1-541.551.561.571.58 o2chlorobenzeneISchemeSchemeSchemeScheme1-591-601-61 k一SchemeSeheme0tandeml-641-631.2 SchemeScheme1.-66 .SchemeSchemeStheme1-67 t’Mark+R43—kSchemeSchemeScheme1-701.711.72R※∞ FFRRtolueneSchemeSchcmcSchcme21-731-741-75 R~I-ISchemen1-76x6 ARlCkScheme2-1 Table.27. and HTable2-l.29. NNTable+NuH—————————1.31. bondTableC-Hofofentries KRRRScheme№№ RR28--carbolines3-1 Br—Scheme3-2

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