《聚（草酸乙二醇酯—co—琥珀酸乙二醇酯）的合成及性能研究》.pdfVIP

维普资讯 第 6期 唐卫华等 ：含氮类亲核试剂对 TICIt／TMPCI／St阳离子聚合作用的研究 6l (WU Guan—ying)．高等学校化学学报 (ChemicalJour— Macromolecules，l998． nalofC，hinese Universities)， l993， l4(10)：l460～ Is] 李树新 (LIShu—xing)，郭文莉 (GUOWen—li)，唐卫华 l663． (TANG Wei—hua)．高分 子材料科学与工程 (Polymer [43 GuoW L，YinHM ，ZhouH．StudyontheRoleofNu— MaterialsScience Engineering)，2000，16(5)：49～ clephiles Carbocationic Polymerization by M olecular 51． Simulation． 37th IUPAC InternationalSymposium on RESEARCH oF NITRoGEN CoNTAINING NUCLEoPHILES RoLE oN M ECHANISM oF PoLYSTYRENE CARBoCATIoNIC PoLYM ERIZATIoN TANG W ci—hua ，GUO W en—li，W U Guan—ying (InstituteofMaterialsScienceandEngineering，Beijing UniversityofChemicalTechnology，BeOing j00029，China 2ChemicalEngineeringDepartment，BeijingInstituteof PetrochemicalTechnology，Beijingj02600，China) ABSTRACT ：The roleofnitrogen containing nucleophiles such asPy，N—M PA ，A—D ，E801as electrondonorsinTMPCI／TiCI4／Stcationicpolymerization system wasdemonstratedbyGPC traces．Theeffectingmechanism ofnitrogencontaining nucleophilesin styrenecationicpolymer— ization wasproposed：when theconcentration ofsuch electron donorswas lowerthan a certain value，they actedasH proton trappers；while，on the contrary they mainly stabilized living propagation centerofthe polymerization system． By comparison，E801was the mosteffective electron donorsamongnitrogencontainingnucleophiles，whichwasconsistentwith theresultof computersimulation，anditseffectonTMPCI／TiCI4／Stpolymerizationsystem wasfurtherinves- tigated． Keywords：livingcenter；electron donors；pyridine；N—methylphenylam ine；A—D ，E801 (上接第 57页。continuedfromP．57) SYNTHESIS，CHARACTERIZA