《N-(1-萘基)马来酰亚胺合成研究》.pdfVIP

王国样等：N一(t一萘基)马束酰亚艘合成研究 绝缘材辑2007．40(5) N一(1一萘基)马来酰亚胺合成研究 王国祥，刘华伟 (湖南理工学院化学化工系。湖南岳用414000) 摘要：以顺丁烯二酸酐和l一萘胺为原料，冰乙酸作溶剂，醋酸酐作脱水荆．无水醋酸钠作催化荆．采用两步法合成了N一 (1一萘基)马来酰亚胺。产物及中问产物采用熔点测定仪、傅立叶红外FT—IR、液相色谱仪等仪器进行了表征．结果表明， 合成产物为目标产品。研究了原料配比、溶剂用量、脱水荆用量、催化剂用量、反应温度、反应时间等工艺条件对反应收率的 影响。确定了最佳工艺条件，使N一(1一萘基)马来酰亚胺的收率达到踞％．纯度达到95．94％。 关键词：N一(1一萘基)马来酰亚胺：合成；表征：工艺条件 中国分类号：TQ323．7；TQ316．3文献标毒码；A 文章绾号：1009—9239(2007)05一∞lO一05 The onthe of Study Synthesis WANGGⅡo．xian卫．LIUHua．wei (H“n口nJ”“ifⅣ坤。，＆i￡月cfdnd nc^nDfp韶；hE妒ng4l蚰叩，傩inn) Abstract：The was with methodinwhichmaleic N—l·Naphthylmaleimide8ynthesi2edtwo-8tep anhydride and weretakenaa aceticacida3 acetic a3 1-napbthylamine ra宵material9，ghciaI80lvent， anhydride and 80di邶Aacetateaa andthe dehydratoranhydrous The were cataly8t．product intermediaryproduct characterized8everaImodern sucha9 by techniques determination analy3is meltingpoint apparatu3． transform Four塘r infrared result9of 8pectroscopy(FT-IR)andliqu试phasechromato毫raphy，etc．The testshowedthatthe wa3the one．Theeffectsofbatch property syntheticproduct g∞l proportionin窑， of and andreaction and tjmeon s01vent， reaction tlIereac- quantity dehydratOrcatalyst． tempefature tion were optimumreactioncondItionswerethusdeterminedthatcanmakethe yjeld inves